Details
| Original language | English |
|---|---|
| Pages (from-to) | 73-82 |
| Number of pages | 10 |
| Journal | Chemical geology |
| Volume | 442 |
| Early online date | 5 Sept 2016 |
| Publication status | Published - 28 Nov 2016 |
Abstract
The viscosity of two series of synthetic alkali silicates, corresponding to Al-bearing pantelleritic and Al-free tri-silicate compositions, has been investigated as a function of temperature, iron redox and Na/(Na + K) ratio. Low temperature (708–1000 K) viscosities were determined by the micropenetration technique in the 109.6 to 1013.6 Pa s range. The effect of Fe2 +/Fetot, from 0.15 to 0.86, was explored for [Na/(Na + K)] ratios from 0 to 1. The results demonstrate a strong decrease of viscosity with the replacement of Na for K in both the Al-bearing and Al-free compositions. In the Al-bearing pantelleritic glasses (Ebu) the viscosity as well as the activation energy for viscous flow decrease with an increase of Fe2 +/Fetot from 0.15 to 0.76. In contrast, no measurable changes in viscosity occur in the Al-free tri-silicate glasses (NFS and KFS) as Fe2 +/Fetot ratio varies from 0.15 to 0.86. The comparison of the pantelleritic glasses with peralkaline compositions from the literature stresses the strong influence of iron redox on the overall viscosity of such melts. This suggests that the contribution of iron species should be accounted for in the calculation of agpaitic index (AI) if magma Fe3 + contents are known. One peculiarity of peralkaline magmas is the excess of alkali to alumina, which generally results in lower viscosities of pantelleritic liquids compared with more common metaluminous rhyolites and exerts a primary control of the rheological behaviour of these melts. Our new viscosity data, combined with existing literature, allow more accurate constraints on the nature and eruption of the pantelleritic magmas. Moreover, the present experimental study can be used to improve the viscosity models that mostly do not take in consideration parameters as iron redox in the viscosity prediction.
Keywords
- Al, Alkali [Na/(Na + K)] ratio, Iron redox, Pantellerite, Tri-silicate glasses, Viscosity
ASJC Scopus subject areas
- Earth and Planetary Sciences(all)
- Geology
- Earth and Planetary Sciences(all)
- Geochemistry and Petrology
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In: Chemical geology, Vol. 442, 28.11.2016, p. 73-82.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Viscosity of pantelleritic and alkali-silicate melts
T2 - Effect of Fe redox state and Na/(Na + K) ratio
AU - Stabile, Paola
AU - Webb, Sharon
AU - Knipping, Jaayke L.
AU - Behrens, Harald
AU - Paris, Eleonora
AU - Giuli, Gabriele
N1 - Funding Information: The authors thank Prof. M.R. Carroll for his contribution and Dr. M.R. Cicconi for useful discussions. This work was supported by grants from FIRB to G.G. (grant n. RBFR082WRU ) and DAAD and Erasmus grants to P.S.
PY - 2016/11/28
Y1 - 2016/11/28
N2 - The viscosity of two series of synthetic alkali silicates, corresponding to Al-bearing pantelleritic and Al-free tri-silicate compositions, has been investigated as a function of temperature, iron redox and Na/(Na + K) ratio. Low temperature (708–1000 K) viscosities were determined by the micropenetration technique in the 109.6 to 1013.6 Pa s range. The effect of Fe2 +/Fetot, from 0.15 to 0.86, was explored for [Na/(Na + K)] ratios from 0 to 1. The results demonstrate a strong decrease of viscosity with the replacement of Na for K in both the Al-bearing and Al-free compositions. In the Al-bearing pantelleritic glasses (Ebu) the viscosity as well as the activation energy for viscous flow decrease with an increase of Fe2 +/Fetot from 0.15 to 0.76. In contrast, no measurable changes in viscosity occur in the Al-free tri-silicate glasses (NFS and KFS) as Fe2 +/Fetot ratio varies from 0.15 to 0.86. The comparison of the pantelleritic glasses with peralkaline compositions from the literature stresses the strong influence of iron redox on the overall viscosity of such melts. This suggests that the contribution of iron species should be accounted for in the calculation of agpaitic index (AI) if magma Fe3 + contents are known. One peculiarity of peralkaline magmas is the excess of alkali to alumina, which generally results in lower viscosities of pantelleritic liquids compared with more common metaluminous rhyolites and exerts a primary control of the rheological behaviour of these melts. Our new viscosity data, combined with existing literature, allow more accurate constraints on the nature and eruption of the pantelleritic magmas. Moreover, the present experimental study can be used to improve the viscosity models that mostly do not take in consideration parameters as iron redox in the viscosity prediction.
AB - The viscosity of two series of synthetic alkali silicates, corresponding to Al-bearing pantelleritic and Al-free tri-silicate compositions, has been investigated as a function of temperature, iron redox and Na/(Na + K) ratio. Low temperature (708–1000 K) viscosities were determined by the micropenetration technique in the 109.6 to 1013.6 Pa s range. The effect of Fe2 +/Fetot, from 0.15 to 0.86, was explored for [Na/(Na + K)] ratios from 0 to 1. The results demonstrate a strong decrease of viscosity with the replacement of Na for K in both the Al-bearing and Al-free compositions. In the Al-bearing pantelleritic glasses (Ebu) the viscosity as well as the activation energy for viscous flow decrease with an increase of Fe2 +/Fetot from 0.15 to 0.76. In contrast, no measurable changes in viscosity occur in the Al-free tri-silicate glasses (NFS and KFS) as Fe2 +/Fetot ratio varies from 0.15 to 0.86. The comparison of the pantelleritic glasses with peralkaline compositions from the literature stresses the strong influence of iron redox on the overall viscosity of such melts. This suggests that the contribution of iron species should be accounted for in the calculation of agpaitic index (AI) if magma Fe3 + contents are known. One peculiarity of peralkaline magmas is the excess of alkali to alumina, which generally results in lower viscosities of pantelleritic liquids compared with more common metaluminous rhyolites and exerts a primary control of the rheological behaviour of these melts. Our new viscosity data, combined with existing literature, allow more accurate constraints on the nature and eruption of the pantelleritic magmas. Moreover, the present experimental study can be used to improve the viscosity models that mostly do not take in consideration parameters as iron redox in the viscosity prediction.
KW - Al
KW - Alkali [Na/(Na + K)] ratio
KW - Iron redox
KW - Pantellerite
KW - Tri-silicate glasses
KW - Viscosity
UR - http://www.scopus.com/inward/record.url?scp=84987621323&partnerID=8YFLogxK
U2 - 10.1016/j.chemgeo.2016.09.003
DO - 10.1016/j.chemgeo.2016.09.003
M3 - Article
AN - SCOPUS:84987621323
VL - 442
SP - 73
EP - 82
JO - Chemical geology
JF - Chemical geology
SN - 0009-2541
ER -