UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Authors

  • Detlev Ristau
  • Winfried Arens
  • Salvador Bosch
  • Angela Duparre
  • Enrico Masetti
  • Damien Jacob
  • George Kiriakidis
  • Francesca Peiro
  • Etienne Quesnel
  • Alexander Tikhonravov

External Research Organisations

  • Universitat de Barcelona
  • Fraunhofer Institute for Applied Optics and Precision Engineering (IOF)
  • ENEA-Cassacia
  • Foundation for Research & Technology - Hellas (FORTH)
  • CEA-LETI
  • Lomonosov Moscow State University
  • Laser Zentrum Hannover e.V. (LZH)
View graph of relations

Details

Original languageEnglish
Title of host publicationAdvances in Optical Interference Coatings
Subtitle of host publication25 - 27 May 1999, Berlin, Germany
Place of PublicationBellingham
PublisherSPIE
Pages436-445
Number of pages10
ISBN (print)0-8194-3212-1
Publication statusPublished - 7 Sept 1999
Externally publishedYes
Event1999 Advances in Optical Interference Coatings - Berlin, Ger
Duration: 25 May 199927 May 1999

Publication series

NameProceedings of SPIE - The International Society for Optical Engineering
PublisherSPIE
Volume3738
ISSN (Print)0277-786X

Abstract

In high quality optical coating systems for the DUV-spectral range, MgF2 is one of the preferred deposition materials. MgF2-coatings exhibit relatively low optical losses as well as high stability and laser induced damage thresholds. In the present joint research effort of several European laboratories, the potentiality of MgF2 is evaluated in respect to the production of improved optical coatings for applications in laser technology and semiconductor lithography. For this purpose, single layers of MgF2 were deposited on superpolished fused silica and CaF2-substrates by ion beam sputtering (IBS, [2]), boat (bPVD) and e-beam (ePVD) evaporation in different laboratories. Besides photometric inspections, the samples were characterized by an optical scatter measurement facility at 193 nm and 633 nm. The structural properties were assessed using AFM, XRD, and adapted TEM-techniques involving conventional thinning methods for the layers. For the measurement of mechanical stress in the coatings, special silicon substrates were coated and analyzed. The optical constants of the MgF2-layers, which were determined by two independent data reduction algorithms from the spectral behaviour, are in good agreement with values published in the open literature: The refractive indices range between 1.40 and 1.41 at 248 nm for the PVD and IBS processes. The IBS-process achieves best homogeneity and lowest surface roughness around 1nmrms among the processes compared. In contrast to PVD coatings, which exhibit tensile mechanical stress ranging approximately from 300 to 400 MPa, high compressive stress of up to 910 MPa occurs in the IBS- coatings. The experimental findings are discussed in respect to the microstructural properties and the surface topography of the coatings.

ASJC Scopus subject areas

Cite this

UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes. / Ristau, Detlev; Arens, Winfried; Bosch, Salvador et al.
Advances in Optical Interference Coatings: 25 - 27 May 1999, Berlin, Germany. Bellingham: SPIE, 1999. p. 436-445 (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 3738).

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Ristau, D, Arens, W, Bosch, S, Duparre, A, Masetti, E, Jacob, D, Kiriakidis, G, Peiro, F, Quesnel, E & Tikhonravov, A 1999, UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes. in Advances in Optical Interference Coatings: 25 - 27 May 1999, Berlin, Germany. Proceedings of SPIE - The International Society for Optical Engineering, vol. 3738, SPIE, Bellingham, pp. 436-445, 1999 Advances in Optical Interference Coatings, Berlin, Ger, 25 May 1999. https://doi.org/10.1117/12.360111
Ristau, D., Arens, W., Bosch, S., Duparre, A., Masetti, E., Jacob, D., Kiriakidis, G., Peiro, F., Quesnel, E., & Tikhonravov, A. (1999). UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes. In Advances in Optical Interference Coatings: 25 - 27 May 1999, Berlin, Germany (pp. 436-445). (Proceedings of SPIE - The International Society for Optical Engineering; Vol. 3738). SPIE. https://doi.org/10.1117/12.360111
Ristau D, Arens W, Bosch S, Duparre A, Masetti E, Jacob D et al. UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes. In Advances in Optical Interference Coatings: 25 - 27 May 1999, Berlin, Germany. Bellingham: SPIE. 1999. p. 436-445. (Proceedings of SPIE - The International Society for Optical Engineering). doi: 10.1117/12.360111
Ristau, Detlev ; Arens, Winfried ; Bosch, Salvador et al. / UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes. Advances in Optical Interference Coatings: 25 - 27 May 1999, Berlin, Germany. Bellingham : SPIE, 1999. pp. 436-445 (Proceedings of SPIE - The International Society for Optical Engineering).
Download
@inproceedings{2deb76a7dab245baacf5cb6a7eb64422,
title = "UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes",
abstract = "In high quality optical coating systems for the DUV-spectral range, MgF2 is one of the preferred deposition materials. MgF2-coatings exhibit relatively low optical losses as well as high stability and laser induced damage thresholds. In the present joint research effort of several European laboratories, the potentiality of MgF2 is evaluated in respect to the production of improved optical coatings for applications in laser technology and semiconductor lithography. For this purpose, single layers of MgF2 were deposited on superpolished fused silica and CaF2-substrates by ion beam sputtering (IBS, [2]), boat (bPVD) and e-beam (ePVD) evaporation in different laboratories. Besides photometric inspections, the samples were characterized by an optical scatter measurement facility at 193 nm and 633 nm. The structural properties were assessed using AFM, XRD, and adapted TEM-techniques involving conventional thinning methods for the layers. For the measurement of mechanical stress in the coatings, special silicon substrates were coated and analyzed. The optical constants of the MgF2-layers, which were determined by two independent data reduction algorithms from the spectral behaviour, are in good agreement with values published in the open literature: The refractive indices range between 1.40 and 1.41 at 248 nm for the PVD and IBS processes. The IBS-process achieves best homogeneity and lowest surface roughness around 1nmrms among the processes compared. In contrast to PVD coatings, which exhibit tensile mechanical stress ranging approximately from 300 to 400 MPa, high compressive stress of up to 910 MPa occurs in the IBS- coatings. The experimental findings are discussed in respect to the microstructural properties and the surface topography of the coatings.",
author = "Detlev Ristau and Winfried Arens and Salvador Bosch and Angela Duparre and Enrico Masetti and Damien Jacob and George Kiriakidis and Francesca Peiro and Etienne Quesnel and Alexander Tikhonravov",
year = "1999",
month = sep,
day = "7",
doi = "10.1117/12.360111",
language = "English",
isbn = "0-8194-3212-1",
series = "Proceedings of SPIE - The International Society for Optical Engineering",
publisher = "SPIE",
pages = "436--445",
booktitle = "Advances in Optical Interference Coatings",
address = "United States",
note = "1999 Advances in Optical Interference Coatings ; Conference date: 25-05-1999 Through 27-05-1999",

}

Download

TY - GEN

T1 - UV-optical and microstructural properties of MgF2-coatings deposited by IBS and PVD processes

AU - Ristau, Detlev

AU - Arens, Winfried

AU - Bosch, Salvador

AU - Duparre, Angela

AU - Masetti, Enrico

AU - Jacob, Damien

AU - Kiriakidis, George

AU - Peiro, Francesca

AU - Quesnel, Etienne

AU - Tikhonravov, Alexander

PY - 1999/9/7

Y1 - 1999/9/7

N2 - In high quality optical coating systems for the DUV-spectral range, MgF2 is one of the preferred deposition materials. MgF2-coatings exhibit relatively low optical losses as well as high stability and laser induced damage thresholds. In the present joint research effort of several European laboratories, the potentiality of MgF2 is evaluated in respect to the production of improved optical coatings for applications in laser technology and semiconductor lithography. For this purpose, single layers of MgF2 were deposited on superpolished fused silica and CaF2-substrates by ion beam sputtering (IBS, [2]), boat (bPVD) and e-beam (ePVD) evaporation in different laboratories. Besides photometric inspections, the samples were characterized by an optical scatter measurement facility at 193 nm and 633 nm. The structural properties were assessed using AFM, XRD, and adapted TEM-techniques involving conventional thinning methods for the layers. For the measurement of mechanical stress in the coatings, special silicon substrates were coated and analyzed. The optical constants of the MgF2-layers, which were determined by two independent data reduction algorithms from the spectral behaviour, are in good agreement with values published in the open literature: The refractive indices range between 1.40 and 1.41 at 248 nm for the PVD and IBS processes. The IBS-process achieves best homogeneity and lowest surface roughness around 1nmrms among the processes compared. In contrast to PVD coatings, which exhibit tensile mechanical stress ranging approximately from 300 to 400 MPa, high compressive stress of up to 910 MPa occurs in the IBS- coatings. The experimental findings are discussed in respect to the microstructural properties and the surface topography of the coatings.

AB - In high quality optical coating systems for the DUV-spectral range, MgF2 is one of the preferred deposition materials. MgF2-coatings exhibit relatively low optical losses as well as high stability and laser induced damage thresholds. In the present joint research effort of several European laboratories, the potentiality of MgF2 is evaluated in respect to the production of improved optical coatings for applications in laser technology and semiconductor lithography. For this purpose, single layers of MgF2 were deposited on superpolished fused silica and CaF2-substrates by ion beam sputtering (IBS, [2]), boat (bPVD) and e-beam (ePVD) evaporation in different laboratories. Besides photometric inspections, the samples were characterized by an optical scatter measurement facility at 193 nm and 633 nm. The structural properties were assessed using AFM, XRD, and adapted TEM-techniques involving conventional thinning methods for the layers. For the measurement of mechanical stress in the coatings, special silicon substrates were coated and analyzed. The optical constants of the MgF2-layers, which were determined by two independent data reduction algorithms from the spectral behaviour, are in good agreement with values published in the open literature: The refractive indices range between 1.40 and 1.41 at 248 nm for the PVD and IBS processes. The IBS-process achieves best homogeneity and lowest surface roughness around 1nmrms among the processes compared. In contrast to PVD coatings, which exhibit tensile mechanical stress ranging approximately from 300 to 400 MPa, high compressive stress of up to 910 MPa occurs in the IBS- coatings. The experimental findings are discussed in respect to the microstructural properties and the surface topography of the coatings.

UR - http://www.scopus.com/inward/record.url?scp=0032664670&partnerID=8YFLogxK

U2 - 10.1117/12.360111

DO - 10.1117/12.360111

M3 - Conference contribution

AN - SCOPUS:0032664670

SN - 0-8194-3212-1

T3 - Proceedings of SPIE - The International Society for Optical Engineering

SP - 436

EP - 445

BT - Advances in Optical Interference Coatings

PB - SPIE

CY - Bellingham

T2 - 1999 Advances in Optical Interference Coatings

Y2 - 25 May 1999 through 27 May 1999

ER -