Use of the inorganic hexacyanoferrate sorbents for analysis of radiocesium in aqueous samples

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Vladimir S. Semenishchev
  • Anna V. Voronina
  • Dharmendra Kumar Gupta

External Research Organisations

  • Ural Federal University (UrFU)
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Details

Original languageEnglish
Pages (from-to)133-139
Number of pages7
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume321
Issue number1
Early online date8 May 2019
Publication statusPublished - 15 Jul 2019

Abstract

Application of two inorganic hexacyanoferrate sorbents (T-35 and NPF-HTD) for radiochemical analysis of 137Cs in various water samples was studied. The results of batch experiment for cesium sorption revealed that both sorbents are suitable for preconcentration of cesium at the pH range of 0.5–11. Column experiments revealed that the NPF-HTD sorbent provided significantly better cesium sorption than the T-35 sorbent due to better sorption kinetics. The sorbents were tested using 1 L of raw and acidified fresh water and seawater as well as 7.2 L water sample from Techa River (activity of 1.36 ± 0.21 Bq L−1 was found). 1.5 g of the NPF-HTD allowed for cesium recovery of 86–98.7% depending on type of water sample.

Keywords

    Cesium-137, Nickel hexacyanoferrate, Sorption, Techa River, Water analysis

ASJC Scopus subject areas

Sustainable Development Goals

Cite this

Use of the inorganic hexacyanoferrate sorbents for analysis of radiocesium in aqueous samples. / Semenishchev, Vladimir S.; Voronina, Anna V.; Gupta, Dharmendra Kumar.
In: Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, No. 1, 15.07.2019, p. 133-139.

Research output: Contribution to journalArticleResearchpeer review

Semenishchev VS, Voronina AV, Gupta DK. Use of the inorganic hexacyanoferrate sorbents for analysis of radiocesium in aqueous samples. Journal of Radioanalytical and Nuclear Chemistry. 2019 Jul 15;321(1):133-139. Epub 2019 May 8. doi: 10.1007/s10967-019-06555-0
Semenishchev, Vladimir S. ; Voronina, Anna V. ; Gupta, Dharmendra Kumar. / Use of the inorganic hexacyanoferrate sorbents for analysis of radiocesium in aqueous samples. In: Journal of Radioanalytical and Nuclear Chemistry. 2019 ; Vol. 321, No. 1. pp. 133-139.
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AU - Semenishchev, Vladimir S.

AU - Voronina, Anna V.

AU - Gupta, Dharmendra Kumar

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