Details
| Original language | English |
|---|---|
| Pages (from-to) | 1541-1542 |
| Number of pages | 2 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 21 |
| Publication status | Published - 1 Dec 1991 |
| Externally published | Yes |
Abstract
An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Molecular Medicine
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In: Journal of the Chemical Society, Chemical Communications, No. 21, 01.12.1991, p. 1541-1542.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Unexpected Proximal Ring Opening Reactions of Benzocyclobutene Complexes
AU - Brands, Michael
AU - Wey, Hans G.
AU - Butenschön, Holger
PY - 1991/12/1
Y1 - 1991/12/1
N2 - An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
AB - An unexpected opening of a proximal bond in the anellated four-membered ring of benzocyclobutene tricarbonylchromium(0) complexes occurs when the 1-hydroxy-1-hex-5-enyl complex 2 is treated with base: in general, rupture of the distal bond is observed. The reaction of tricarbonyl-η6-(1- oxobenzocyclobutene)chromium(0) 1 with primary amines also causes a proximal ring-opening reaction.
UR - http://www.scopus.com/inward/record.url?scp=0026055184&partnerID=8YFLogxK
U2 - 10.1039/C39910001541
DO - 10.1039/C39910001541
M3 - Article
AN - SCOPUS:0026055184
SP - 1541
EP - 1542
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
SN - 0022-4936
IS - 21
ER -