Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe

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Authors

  • Frank Edelmann
  • Peter Behrens
  • Sabine Behrens
  • Ulrich Behrens

External Research Organisations

  • Universität Hamburg
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Details

Original languageGerman
Pages (from-to)109-116
Number of pages8
JournalJournal of Organometallic Chemistry
Volume309
Issue number1-2
Publication statusPublished - 1986
Externally publishedYes

Abstract

Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.

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Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe. / Edelmann, Frank; Behrens, Peter; Behrens, Sabine et al.
In: Journal of Organometallic Chemistry, Vol. 309, No. 1-2, 1986, p. 109-116.

Research output: Contribution to journalArticleResearchpeer review

Edelmann F, Behrens P, Behrens S, Behrens U. Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe. Journal of Organometallic Chemistry. 1986;309(1-2):109-116. doi: 10.1016/S0022-328X(00)99577-9
Edelmann, Frank ; Behrens, Peter ; Behrens, Sabine et al. / Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe. In: Journal of Organometallic Chemistry. 1986 ; Vol. 309, No. 1-2. pp. 109-116.
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abstract = "Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.",
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AU - Behrens, Sabine

AU - Behrens, Ulrich

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