Details
| Original language | German |
|---|---|
| Pages (from-to) | 109-116 |
| Number of pages | 8 |
| Journal | Journal of Organometallic Chemistry |
| Volume | 309 |
| Issue number | 1-2 |
| Publication status | Published - 1986 |
| Externally published | Yes |
Abstract
Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
- Chemistry(all)
- Inorganic Chemistry
- Materials Science(all)
- Materials Chemistry
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In: Journal of Organometallic Chemistry, Vol. 309, No. 1-2, 1986, p. 109-116.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Übergangsmetall-fulven-komplexe. XXVII. Basische fulven-komplexe
AU - Edelmann, Frank
AU - Behrens, Peter
AU - Behrens, Sabine
AU - Behrens, Ulrich
PY - 1986
Y1 - 1986
N2 - Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.
AB - Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1 : 1 adducts. The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand. The first crystalline protonation product of a fulvene complex was obtained by treatment of [η5-6,6-bis(dimethylamino)fulvene]Cr(CO)3 with HBF4.
UR - http://www.scopus.com/inward/record.url?scp=3242682267&partnerID=8YFLogxK
U2 - 10.1016/S0022-328X(00)99577-9
DO - 10.1016/S0022-328X(00)99577-9
M3 - Artikel
AN - SCOPUS:3242682267
VL - 309
SP - 109
EP - 116
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1-2
ER -