Details
| Original language | English |
|---|---|
| Article number | 109981 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 296 |
| Publication status | Published - Apr 2020 |
| Externally published | Yes |
Abstract
The new zeolite RUB-5 and the new phyllo silicate RUB-6 were synthesized at temperatures between 130 °C and 200 °C from reaction mixtures consisting of SiO2/LiOH/B(OH)3/OA/H2O or SiO2/KOH/OA/H2O (OA = organic additive). Physico-chemical characterization using solid-state NMR spectroscopy, SEM, TG-DTA, and ATR-FTIR spectroscopy confirmed that RUB-5 is a framework silicate while RUB-6 is a layer silicate. The XRD powder patterns were indexed in monoclinic symmetry (space group: C2) with lattice parameters of a0 = 10.2699 (4) Å, b0 = 10.6556 (4) Å, c0 = 18.1551 (7) Å and β = 106.35 (1)° (RUB-5), and a0 = 10.1100 (43) Å, b0 = 10.6956 (51) Å, c0 = 20.5448 (44) Å and β = 105.79 (1)° (RUB-6). The chemical compositions of RUB-5 and RUB-6 are [Si42O84] (with a few silanol defects) and [Si40O76(OH)8] • C6H14N2, respectively. According to the XRD powder patterns, RUB-5 and RUB-6 have a disordered structure and belong to the Silica-X family of materials. The materials are structurally closely related and contain topologically identical, dense layer-like building units, named γ-layer. In the case of RUB-5 these building units are interconnected via additional Si atoms leading to a 2-dimensional pore system consisting of intersecting 8-ring channels. RUB-5 is a pure silica zeolite of very high density (2.20 g/cm3) which shows a negative thermal expansion between 20 °C and 470 °C. In the case of RUB-6, the layers are intercalated by organic cations which generate weak ionic bonds between cation and silicate layer. Formally, RUB-6 may be transformed into RUB-5 via a condensation reaction involving the γ-layers ([Si40O76(OH)8]) of RUB-6 and additional Si(OH)4 units from the reaction mixture to form the framework of RUB-5 ([Si42O84]) and water. In this sense, RUB-5 is the interlayer expanded zeolite based on the silicate layers of RUB-6.
Keywords
- Layered silicate, Negative thermal expansion, Silica-X, Synthesis, Zeolite
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
- Engineering(all)
- Mechanics of Materials
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In: Microporous and Mesoporous Materials, Vol. 296, 109981, 04.2020.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Two new members of the Silica-X family of materials
T2 - RUB-5, a silica zeolite with a very high framework density and RUB-6, a hydrous layer silicate
AU - Marler, Bernd
AU - Krysiak, Yaşar
AU - Kolb, Ute
AU - Grafweg, Christine
AU - Gies, Hermann
N1 - Publisher Copyright: © 2019
PY - 2020/4
Y1 - 2020/4
N2 - The new zeolite RUB-5 and the new phyllo silicate RUB-6 were synthesized at temperatures between 130 °C and 200 °C from reaction mixtures consisting of SiO2/LiOH/B(OH)3/OA/H2O or SiO2/KOH/OA/H2O (OA = organic additive). Physico-chemical characterization using solid-state NMR spectroscopy, SEM, TG-DTA, and ATR-FTIR spectroscopy confirmed that RUB-5 is a framework silicate while RUB-6 is a layer silicate. The XRD powder patterns were indexed in monoclinic symmetry (space group: C2) with lattice parameters of a0 = 10.2699 (4) Å, b0 = 10.6556 (4) Å, c0 = 18.1551 (7) Å and β = 106.35 (1)° (RUB-5), and a0 = 10.1100 (43) Å, b0 = 10.6956 (51) Å, c0 = 20.5448 (44) Å and β = 105.79 (1)° (RUB-6). The chemical compositions of RUB-5 and RUB-6 are [Si42O84] (with a few silanol defects) and [Si40O76(OH)8] • C6H14N2, respectively. According to the XRD powder patterns, RUB-5 and RUB-6 have a disordered structure and belong to the Silica-X family of materials. The materials are structurally closely related and contain topologically identical, dense layer-like building units, named γ-layer. In the case of RUB-5 these building units are interconnected via additional Si atoms leading to a 2-dimensional pore system consisting of intersecting 8-ring channels. RUB-5 is a pure silica zeolite of very high density (2.20 g/cm3) which shows a negative thermal expansion between 20 °C and 470 °C. In the case of RUB-6, the layers are intercalated by organic cations which generate weak ionic bonds between cation and silicate layer. Formally, RUB-6 may be transformed into RUB-5 via a condensation reaction involving the γ-layers ([Si40O76(OH)8]) of RUB-6 and additional Si(OH)4 units from the reaction mixture to form the framework of RUB-5 ([Si42O84]) and water. In this sense, RUB-5 is the interlayer expanded zeolite based on the silicate layers of RUB-6.
AB - The new zeolite RUB-5 and the new phyllo silicate RUB-6 were synthesized at temperatures between 130 °C and 200 °C from reaction mixtures consisting of SiO2/LiOH/B(OH)3/OA/H2O or SiO2/KOH/OA/H2O (OA = organic additive). Physico-chemical characterization using solid-state NMR spectroscopy, SEM, TG-DTA, and ATR-FTIR spectroscopy confirmed that RUB-5 is a framework silicate while RUB-6 is a layer silicate. The XRD powder patterns were indexed in monoclinic symmetry (space group: C2) with lattice parameters of a0 = 10.2699 (4) Å, b0 = 10.6556 (4) Å, c0 = 18.1551 (7) Å and β = 106.35 (1)° (RUB-5), and a0 = 10.1100 (43) Å, b0 = 10.6956 (51) Å, c0 = 20.5448 (44) Å and β = 105.79 (1)° (RUB-6). The chemical compositions of RUB-5 and RUB-6 are [Si42O84] (with a few silanol defects) and [Si40O76(OH)8] • C6H14N2, respectively. According to the XRD powder patterns, RUB-5 and RUB-6 have a disordered structure and belong to the Silica-X family of materials. The materials are structurally closely related and contain topologically identical, dense layer-like building units, named γ-layer. In the case of RUB-5 these building units are interconnected via additional Si atoms leading to a 2-dimensional pore system consisting of intersecting 8-ring channels. RUB-5 is a pure silica zeolite of very high density (2.20 g/cm3) which shows a negative thermal expansion between 20 °C and 470 °C. In the case of RUB-6, the layers are intercalated by organic cations which generate weak ionic bonds between cation and silicate layer. Formally, RUB-6 may be transformed into RUB-5 via a condensation reaction involving the γ-layers ([Si40O76(OH)8]) of RUB-6 and additional Si(OH)4 units from the reaction mixture to form the framework of RUB-5 ([Si42O84]) and water. In this sense, RUB-5 is the interlayer expanded zeolite based on the silicate layers of RUB-6.
KW - Layered silicate
KW - Negative thermal expansion
KW - Silica-X
KW - Synthesis
KW - Zeolite
UR - http://www.scopus.com/inward/record.url?scp=85076959355&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2019.109981
DO - 10.1016/j.micromeso.2019.109981
M3 - Article
AN - SCOPUS:85076959355
VL - 296
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
M1 - 109981
ER -