Details
| Original language | English |
|---|---|
| Article number | ss-2018-z0731-sr |
| Pages (from-to) | 161-177 |
| Number of pages | 17 |
| Journal | Synthesis (Germany) |
| Volume | 51 |
| Issue number | 1 |
| Early online date | 27 Nov 2018 |
| Publication status | Published - Jan 2019 |
Abstract
Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
Keywords
- catalysis, cross-couplings, Fe(acac), hydrogen atom transfer, radical transformations, synthetic chemistry, tris(acetylacetonato) iron(III)
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Synthesis (Germany), Vol. 51, No. 1, ss-2018-z0731-sr, 01.2019, p. 161-177.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
AU - Lübken, Dennis
AU - Saxarra, Marius
AU - Kalesse, Markus
PY - 2019/1
Y1 - 2019/1
N2 - Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
AB - Tris(acetylacetonato) iron(III) [Fe(acac) 3 ] is an indispensable reagent in synthetic chemistry. Its applications range from hydrogen atom transfer to cross-coupling reactions and to use as a Lewis acid. Consequently, the exceptional utility of Fe(acac) 3 has been demonstrated in several total syntheses. This short review summarizes the applications of Fe(acac) 3 in methodology and catalysis and highlights its use for the synthesis of medicinally relevant structures and in natural product syntheses. 1 Introduction 2 Hydrogen Atom Transfer (HAT) 3 Oxidations and Radical Transformations 4 Synthesis and Use of Alkynes and Allenes 5 Cross-Couplings and Cycloisomerizations 6 Borylations 7 Miscellaneous Reactions 8 Conclusions.
KW - catalysis
KW - cross-couplings
KW - Fe(acac)
KW - hydrogen atom transfer
KW - radical transformations
KW - synthetic chemistry
KW - tris(acetylacetonato) iron(III)
UR - http://www.scopus.com/inward/record.url?scp=85058518887&partnerID=8YFLogxK
U2 - 10.1055/s-0037-1610393
DO - 10.1055/s-0037-1610393
M3 - Article
AN - SCOPUS:85058518887
VL - 51
SP - 161
EP - 177
JO - Synthesis (Germany)
JF - Synthesis (Germany)
SN - 0039-7881
IS - 1
M1 - ss-2018-z0731-sr
ER -