Details
| Original language | English |
|---|---|
| Pages (from-to) | 479-482 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 7 |
| Issue number | 3 |
| Publication status | Published - 13 Jan 2005 |
Abstract
(Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
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In: Organic Letters, Vol. 7, No. 3, 13.01.2005, p. 479-482.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Total synthesis and elucidation of the absolute configuration of the diterpene tonantzitlolone
AU - Jasper, Christian
AU - Wittenberg, Rüdiger
AU - Quitschalle, Monika
AU - Jakupovic, Jasmin
AU - Kirschning, Andreas
PY - 2005/1/13
Y1 - 2005/1/13
N2 - (Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
AB - (Chemical Equation Presented) The first enantioselective total synthesis of tonantzitlolone, a novel 15-membered macrocyclic diterpene, utilized a Julia olefination, a highly selective, potassium enolate-based anti-Felkin aldol reaction, and an E-selective ring-closing metathesis as key C-C bond-forming steps. The absolute configuration of tonantzitlolone is established.
UR - http://www.scopus.com/inward/record.url?scp=13844272566&partnerID=8YFLogxK
UR - https://pubs.acs.org/doi/10.1021/ol0504401
U2 - 10.1021/ol047559e
DO - 10.1021/ol047559e
M3 - Article
C2 - 15673269
AN - SCOPUS:13844272566
VL - 7
SP - 479
EP - 482
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 3
ER -