Thermodynamic view on the loss mechanisms in PEM-fuel cells

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Authors

  • S. Kabelac
  • M. Siemer

External Research Organisations

  • Helmut Schmidt University
View graph of relations

Details

Original languageEnglish
Title of host publicationASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems
Subtitle of host publication3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005
PublisherAmerican Society of Mechanical Engineers(ASME)
Pages405-411
Number of pages7
ISBN (print)0791837645, 9780791837641
Publication statusPublished - 2005
Externally publishedYes
Event3rd International Conference on Fuel Cell Science, Engineering, and Technology, 2005 - Ypsilanti, MI, United States
Duration: 23 May 200525 May 2005
Conference number: 3

Abstract

The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.

ASJC Scopus subject areas

Cite this

Thermodynamic view on the loss mechanisms in PEM-fuel cells. / Kabelac, S.; Siemer, M.
ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME), 2005. p. 405-411 FUELCELL2005-74071.

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Kabelac, S & Siemer, M 2005, Thermodynamic view on the loss mechanisms in PEM-fuel cells. in ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005., FUELCELL2005-74071, American Society of Mechanical Engineers(ASME), pp. 405-411, 3rd International Conference on Fuel Cell Science, Engineering, and Technology, 2005, Ypsilanti, MI, Michigan, United States, 23 May 2005. https://doi.org/10.1115/fuelcell2005-74071
Kabelac, S., & Siemer, M. (2005). Thermodynamic view on the loss mechanisms in PEM-fuel cells. In ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005 (pp. 405-411). Article FUELCELL2005-74071 American Society of Mechanical Engineers(ASME). https://doi.org/10.1115/fuelcell2005-74071
Kabelac S, Siemer M. Thermodynamic view on the loss mechanisms in PEM-fuel cells. In ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME). 2005. p. 405-411. FUELCELL2005-74071 doi: 10.1115/fuelcell2005-74071
Kabelac, S. ; Siemer, M. / Thermodynamic view on the loss mechanisms in PEM-fuel cells. ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems: 3rd International Conference on Fuel Cell Science, Engineering and Technology. Ypsilanti, Michigan, USA. May 23–25, 2005. American Society of Mechanical Engineers(ASME), 2005. pp. 405-411
Download
@inproceedings{4507f34f75eb49af88e238fdc4f8e6dd,
title = "Thermodynamic view on the loss mechanisms in PEM-fuel cells",
abstract = "The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.",
author = "S. Kabelac and M. Siemer",
note = "Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; 3rd International Conference on Fuel Cell Science, Engineering, and Technology, 2005 ; Conference date: 23-05-2005 Through 25-05-2005",
year = "2005",
doi = "10.1115/fuelcell2005-74071",
language = "English",
isbn = "0791837645",
pages = "405--411",
booktitle = "ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems",
publisher = "American Society of Mechanical Engineers(ASME)",
address = "United States",

}

Download

TY - GEN

T1 - Thermodynamic view on the loss mechanisms in PEM-fuel cells

AU - Kabelac, S.

AU - Siemer, M.

N1 - Conference code: 3

PY - 2005

Y1 - 2005

N2 - The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.

AB - The fuel cell, which is a highly promising candidate for high efficiency energy conversion, is not reaching expected conversion efficiencies of η > 0,5 yet. Parallel to standard explanations of loss mechanisms by means of overvoltages, a thermodynamic view of addressing irreversibilities by calculating local entropy production rates is helpful. Entropy production rates are calculated by multiplying local transport fluxes with appropriate driving forces, i.e., gradients of temperature, chemical potentials and electric potentials. These gradients have to be calculated by solving the set of constitutive balance equations. Before this tedious task is done, simplified model equations have to be used. The reversible fuel cell is the starting point of analysis. Results for a one-dimensional PEM-FC are shown.

UR - http://www.scopus.com/inward/record.url?scp=27744474790&partnerID=8YFLogxK

U2 - 10.1115/fuelcell2005-74071

DO - 10.1115/fuelcell2005-74071

M3 - Conference contribution

AN - SCOPUS:27744474790

SN - 0791837645

SN - 9780791837641

SP - 405

EP - 411

BT - ASME 2005 Summer Heat Transfer Conference collocated with the ASME 2005 Pacific Rim Technical Conference and Exhibition on Integration and Packaging of MEMS, NEMS, and Electronic Systems

PB - American Society of Mechanical Engineers(ASME)

T2 - 3rd International Conference on Fuel Cell Science, Engineering, and Technology, 2005

Y2 - 23 May 2005 through 25 May 2005

ER -