Details
| Original language | English |
|---|---|
| Pages (from-to) | 597-599 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 3 |
| Publication status | Published - 2008 |
Abstract
(Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
Keywords
- Chlorotonil, Cross-coupling, Cycloaddition, Olefination, Total synthesis
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
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In: Angewandte Chemie - International Edition, Vol. 47, No. 3, 2008, p. 597-599.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The total synthesis of chlorotonil A
AU - Rahn, Nicola
AU - Kalesse, Markus
PY - 2008
Y1 - 2008
N2 - (Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
AB - (Chemical Equation Presented) Stacking the deck: The natural product chloronitril A contains an unprecedented motif in which a CCl2 unit in a 14-membered macrolide framework is flanked by two carbonyl groups. In the first total synthesis of chlorotonil A a highly selective intramolecular Diels-Alder reaction was employed to generate the decalin system.
KW - Chlorotonil
KW - Cross-coupling
KW - Cycloaddition
KW - Olefination
KW - Total synthesis
UR - http://www.scopus.com/inward/record.url?scp=38949192053&partnerID=8YFLogxK
U2 - 10.1002/anie.200703930
DO - 10.1002/anie.200703930
M3 - Article
C2 - 18041801
AN - SCOPUS:38949192053
VL - 47
SP - 597
EP - 599
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 3
ER -