The Rotational Spectrum of the Fluorobenzene-Argon Van der Waals Complex

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Authors

  • W. Stahl
  • J. U. Grabow

External Research Organisations

  • Kiel University
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Details

Original languageEnglish
Pages (from-to)681-684
Number of pages4
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume47
Issue number5
Publication statusPublished - 1 May 1992

Abstract

The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.

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The Rotational Spectrum of the Fluorobenzene-Argon Van der Waals Complex. / Stahl, W.; Grabow, J. U.
In: Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, Vol. 47, No. 5, 01.05.1992, p. 681-684.

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abstract = "The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.",
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Download

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AU - Stahl, W.

AU - Grabow, J. U.

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AB - The rotational spectrum of the fluorobenzene-argon complex has been studied in the microwave region between 7 and 18 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were found to be A = 1811.81369(11) MHz, B= 1105.12965(15) MHz, C = 901.84281 (5) MHz, the centrifugal distortion constants are ΔJ= 2.6886(17) kHz, ΔJK = 8.3761 (52) kHz ΔK = -8.278(5) kHz, δJ=0.65993(72) kHz, and δK= 6.013(11) kHz. The argon atom is placed 3.55 A above the ring plane.

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