Details
| Original language | English |
|---|---|
| Pages (from-to) | 593-600 |
| Number of pages | 8 |
| Journal | Russian Journal of Physical Chemistry B |
| Volume | 6 |
| Issue number | 5 |
| Publication status | Published - 15 Nov 2012 |
Abstract
Microporous framework aluminosilicates with the cancrinite- and sodalite-type structures containing NO3-, CO 32-, SO42-, C2O 42- and PO43-, as extra-framework anions were synthesized under hydrothermal conditions at temperatures from 160 to 200°C. SO42- exhibits the highest affinity to cancrinite structure at the competition of various X anions. Chemical composition, X-ray diffractometry characteristics, and IR spectra of the compounds obtained, as well as kinetics and mechanism of thermal transformations of nitrate counterpart of cancrinite, were studied.
Keywords
- Cancrinite, Hydrothermal synthesis, Sodalite
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Russian Journal of Physical Chemistry B, Vol. 6, No. 5, 15.11.2012, p. 593-600.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The role of additional anions in microporous aluminosilicates with cancrinite-type framework
AU - Chukanov, N. V.
AU - Nedelko, V. V.
AU - Blinova, L. N.
AU - Korshunova, L. A.
AU - Olysych, L. V.
AU - Lykova, I. S.
AU - Pekov, I. V.
AU - Buhl, J. C.
AU - Depmeier, W.
N1 - Funding Information: The work was supported by the Russian Founda tion for Basic Research (project nos. 11 05 91331 NNIO_a and 11 05 00407_a).
PY - 2012/11/15
Y1 - 2012/11/15
N2 - Microporous framework aluminosilicates with the cancrinite- and sodalite-type structures containing NO3-, CO 32-, SO42-, C2O 42- and PO43-, as extra-framework anions were synthesized under hydrothermal conditions at temperatures from 160 to 200°C. SO42- exhibits the highest affinity to cancrinite structure at the competition of various X anions. Chemical composition, X-ray diffractometry characteristics, and IR spectra of the compounds obtained, as well as kinetics and mechanism of thermal transformations of nitrate counterpart of cancrinite, were studied.
AB - Microporous framework aluminosilicates with the cancrinite- and sodalite-type structures containing NO3-, CO 32-, SO42-, C2O 42- and PO43-, as extra-framework anions were synthesized under hydrothermal conditions at temperatures from 160 to 200°C. SO42- exhibits the highest affinity to cancrinite structure at the competition of various X anions. Chemical composition, X-ray diffractometry characteristics, and IR spectra of the compounds obtained, as well as kinetics and mechanism of thermal transformations of nitrate counterpart of cancrinite, were studied.
KW - Cancrinite
KW - Hydrothermal synthesis
KW - Sodalite
UR - http://www.scopus.com/inward/record.url?scp=84891774901&partnerID=8YFLogxK
U2 - 10.1134/S1990793112050120
DO - 10.1134/S1990793112050120
M3 - Article
AN - SCOPUS:84891774901
VL - 6
SP - 593
EP - 600
JO - Russian Journal of Physical Chemistry B
JF - Russian Journal of Physical Chemistry B
SN - 1990-7931
IS - 5
ER -