Details
| Original language | English |
|---|---|
| Pages (from-to) | 1240-1243 |
| Number of pages | 4 |
| Journal | Inorganica chimica acta |
| Volume | 360 |
| Issue number | 3 |
| Publication status | Published - 15 Feb 2007 |
Abstract
The rotational spectra of three isotopologues of dichlorodimethylgermane were measured by free jet absorption millimeterwave spectroscopy. A partial r0 structure was obtained. The barrier to internal rotation of the methyl groups is too high to cause splittings observable within our spectral resolution. Corresponding to the resolving power of the experiment, the lower limit to the V3 barrier is about 5.8 kJ/mol.
Keywords
- Free jets, Germane derivatives, Molecular structure, Organometallics, Rotational spectra
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Inorganic Chemistry
- Materials Science(all)
- Materials Chemistry
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In: Inorganica chimica acta, Vol. 360, No. 3, 15.02.2007, p. 1240-1243.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The mm-wave rotational spectrum of dichlorodimethylgermane
AU - Ottaviani, Paolo
AU - Caminati, Walther
AU - Schnell, Melanie
AU - Grabow, Jens Uwe
N1 - Funding Information: We thank the Ministero dell’Istruzione, dell’Università e della Ricerca (MIUR) and the German Academic Exchange Service for funding the exchange visits between the Bologna and Hannover research groups (DAAD Projekt D/0231300 and Progetto VIGONI 2003 21-2002).
PY - 2007/2/15
Y1 - 2007/2/15
N2 - The rotational spectra of three isotopologues of dichlorodimethylgermane were measured by free jet absorption millimeterwave spectroscopy. A partial r0 structure was obtained. The barrier to internal rotation of the methyl groups is too high to cause splittings observable within our spectral resolution. Corresponding to the resolving power of the experiment, the lower limit to the V3 barrier is about 5.8 kJ/mol.
AB - The rotational spectra of three isotopologues of dichlorodimethylgermane were measured by free jet absorption millimeterwave spectroscopy. A partial r0 structure was obtained. The barrier to internal rotation of the methyl groups is too high to cause splittings observable within our spectral resolution. Corresponding to the resolving power of the experiment, the lower limit to the V3 barrier is about 5.8 kJ/mol.
KW - Free jets
KW - Germane derivatives
KW - Molecular structure
KW - Organometallics
KW - Rotational spectra
UR - http://www.scopus.com/inward/record.url?scp=33846256260&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2006.07.114
DO - 10.1016/j.ica.2006.07.114
M3 - Article
AN - SCOPUS:33846256260
VL - 360
SP - 1240
EP - 1243
JO - Inorganica chimica acta
JF - Inorganica chimica acta
SN - 0020-1693
IS - 3
ER -