Details
| Original language | English |
|---|---|
| Pages (from-to) | 229-232 |
| Number of pages | 4 |
| Journal | Zeitschrift für Naturforschung - Section A Physical Sciences |
| Volume | 46 |
| Issue number | 3 |
| Publication status | Published - 1 Mar 1991 |
Abstract
We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.
ASJC Scopus subject areas
- Mathematics(all)
- Mathematical Physics
- Physics and Astronomy(all)
- General Physics and Astronomy
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Zeitschrift für Naturforschung - Section A Physical Sciences, Vol. 46, No. 3, 01.03.1991, p. 229-232.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The Microwave Spectrum and Dipole Moment of Hexafluoropropanone
AU - Grabow, J. U.
AU - Heineking, N.
AU - Stahl, W.
N1 - Funding Information: We thank the members of our group for help and discussion. Funds of the Deutsche Forschungsgemeinschaft, the Land Schleswig-Holstein and the Fonds der Chemie are gratefully acknowledged.
PY - 1991/3/1
Y1 - 1991/3/1
N2 - We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.
AB - We recorded the microwave spectrum of hexafluoropropanone between 7 and 15 GHz using a pulsed molecular beam microwave Fourier transform spectrometer. The rotational constants were determined to be A =2181.71980(14) MHz, B= 1037.22930(7) MHz, C = 934.89233(8) MHz, the quartic centrifugal distortion constants are D1j = 0.07378(39) kHz, D'JK= 0.10002(75) kHz, D'K = -0.07269(266) kHz, σ'J = 0.00623(29) kHz and R'6= 0.00755(12) kHz. Stark effect measurements yielded a dipole moment µ = ub= 0.3949(18) D.
UR - http://www.scopus.com/inward/record.url?scp=0000105856&partnerID=8YFLogxK
U2 - 10.1515/zna-1991-0303
DO - 10.1515/zna-1991-0303
M3 - Article
AN - SCOPUS:0000105856
VL - 46
SP - 229
EP - 232
JO - Zeitschrift für Naturforschung - Section A Physical Sciences
JF - Zeitschrift für Naturforschung - Section A Physical Sciences
SN - 0932-0784
IS - 3
ER -