Details
| Original language | English |
|---|---|
| Pages (from-to) | 9658-9662 |
| Number of pages | 5 |
| Journal | Journal of Chemical Physics |
| Volume | 116 |
| Issue number | 22 |
| Publication status | Published - 22 May 2002 |
| Externally published | Yes |
Abstract
The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- General Physics and Astronomy
- Chemistry(all)
- Physical and Theoretical Chemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: Journal of Chemical Physics, Vol. 116, No. 22, 22.05.2002, p. 9658-9662.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The influence of internal degrees of freedom on the unimolecular decay of the molecule-cluster compound Au8+CH3OH
AU - Vogel, Manuel
AU - Hansen, Klavs
AU - Herlert, A.
AU - Schweikhard, L.
AU - Walther, Clemens
PY - 2002/5/22
Y1 - 2002/5/22
N2 - The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
AB - The measurements of time-resolved photodissociation of the sequential reaction Au8+CH3OH→Au8+→ Au7+ were performed for several excitation energies. The yields and production rates of the final state Au7+ in the sequential process were found to be strongly influenced by the excitation energy deposited into the evaporated methanol molecule. Both the yields and rate constants could be fitted with a single parameter, which is the binding energy of the cluster-methanol.
UR - http://www.scopus.com/inward/record.url?scp=0037042629&partnerID=8YFLogxK
U2 - 10.1063/1.1476934
DO - 10.1063/1.1476934
M3 - Article
AN - SCOPUS:0037042629
VL - 116
SP - 9658
EP - 9662
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 22
ER -