Details
Original language | English |
---|---|
Pages (from-to) | 7-11 |
Number of pages | 5 |
Journal | Journal of molecular spectroscopy |
Volume | 300 |
Early online date | 19 Feb 2014 |
Publication status | Published - Jun 2014 |
Abstract
The pure rotational spectrum of a minor isotopologue of ytterbium fluoride, 171YbF, in the X2Σ+ (v = 0) state has been recorded using Fourier transform microwave (FTMW) spectroscopy and pump/probe microwave optical double resonance (PPMODR) spectroscopy. The pure rotational spectra and precisely measured splittings in the (0, 0) A 2Π1/2 ← X2Σ+ band were analyzed to produce an improved set of fine and magnetic hyperfine parameters for the X2Σ+ (v = 0) state of 171YbF. A comparison with theoretical predictions is made.
Keywords
- Odd isotope, Rotational spectrum, Ytterbium fluoride
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Journal of molecular spectroscopy, Vol. 300, 06.2014, p. 7-11.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - The hyperfine interaction in the odd isotope of ytterbium fluoride, 171YbF
AU - Glassman, Zachary
AU - Mawhorter, Richard
AU - Grabow, Jens Uwe
AU - Le, Anh
AU - Steimle, Timothy C.
N1 - Funding Information: The research at ASU has been supported by a grant from the National Science Foundation (CSDM-A; CHE-1265885) (Steimle). The research at Gottfried-Wilhelm-Leibniz-Universität was supported by a grants form Deutsche Forschungsgemeinschaft (DFG) (Grabow), Land Niedersachsen (Grabow) and the Deutscher Akademischer Austauschdienst (DAAD) (Mawhorter), a Pomona College Sontag Research Fellowship (Mawhorter and Glassman), and the Sherman Fairchild Foundation (Glassman).
PY - 2014/6
Y1 - 2014/6
N2 - The pure rotational spectrum of a minor isotopologue of ytterbium fluoride, 171YbF, in the X2Σ+ (v = 0) state has been recorded using Fourier transform microwave (FTMW) spectroscopy and pump/probe microwave optical double resonance (PPMODR) spectroscopy. The pure rotational spectra and precisely measured splittings in the (0, 0) A 2Π1/2 ← X2Σ+ band were analyzed to produce an improved set of fine and magnetic hyperfine parameters for the X2Σ+ (v = 0) state of 171YbF. A comparison with theoretical predictions is made.
AB - The pure rotational spectrum of a minor isotopologue of ytterbium fluoride, 171YbF, in the X2Σ+ (v = 0) state has been recorded using Fourier transform microwave (FTMW) spectroscopy and pump/probe microwave optical double resonance (PPMODR) spectroscopy. The pure rotational spectra and precisely measured splittings in the (0, 0) A 2Π1/2 ← X2Σ+ band were analyzed to produce an improved set of fine and magnetic hyperfine parameters for the X2Σ+ (v = 0) state of 171YbF. A comparison with theoretical predictions is made.
KW - Odd isotope
KW - Rotational spectrum
KW - Ytterbium fluoride
UR - http://www.scopus.com/inward/record.url?scp=84901627837&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2014.02.003
DO - 10.1016/j.jms.2014.02.003
M3 - Article
AN - SCOPUS:84901627837
VL - 300
SP - 7
EP - 11
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
SN - 0022-2852
ER -