Details
| Original language | English |
|---|---|
| Title of host publication | Design, Development, and Applications of Engineering Ceramics and Composites - A Collection of Papers Presented at the 8th Pacific Rim Conference on Ceramic and Glass Technology, PACRIM 8 |
| Publisher | American Ceramic Society |
| Pages | 315-324 |
| Number of pages | 10 |
| ISBN (print) | 9780470889367 |
| Publication status | Published - 28 Jun 2010 |
| Event | 8th Pacific Rim Conference on Ceramic and Glass Technology, PACRIM-8 - Vancouver, BC, Canada Duration: 31 May 2009 → 5 Jun 2009 |
Publication series
| Name | Ceramic Transactions |
|---|---|
| Volume | 215 |
| ISSN (Print) | 1042-1122 |
Abstract
The ageing of metakaolin-based geopolymer of special composition (1.2K 2O·Al2O3·4.2SiO 2· 14H2O) has been studied by flexural force measurements, a molybdate analytical method and Fourier transform infrared spectroscopy (FTIR). The results enable new insight into details of the structural development responsible for early strength development between 25 h and 100 h and the unfavorable weakening for ageing above 200 h. In particular the increase in strength is related to the slow development of an aluminosilicate network enclosing preformed polysilicate chains. A fast condensation of silicate chains occurs during the dissolution of metakaolin in the first 25 h of the ageing process. The subsequent destruction of polymeric silicate chains finally causes the weakening.
ASJC Scopus subject areas
- Materials Science(all)
- Ceramics and Composites
- Materials Science(all)
- Materials Chemistry
Cite this
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Design, Development, and Applications of Engineering Ceramics and Composites - A Collection of Papers Presented at the 8th Pacific Rim Conference on Ceramic and Glass Technology, PACRIM 8. American Ceramic Society, 2010. p. 315-324 (Ceramic Transactions; Vol. 215).
Research output: Chapter in book/report/conference proceeding › Conference contribution › Research › peer review
}
TY - GEN
T1 - The ageing process of alkali activated metakaolin
AU - Rüscher, C. H.
AU - Mielcarek, E.
AU - Lutz, W.
AU - Ritzmann, A.
AU - Kriven, W. M.
PY - 2010/6/28
Y1 - 2010/6/28
N2 - The ageing of metakaolin-based geopolymer of special composition (1.2K 2O·Al2O3·4.2SiO 2· 14H2O) has been studied by flexural force measurements, a molybdate analytical method and Fourier transform infrared spectroscopy (FTIR). The results enable new insight into details of the structural development responsible for early strength development between 25 h and 100 h and the unfavorable weakening for ageing above 200 h. In particular the increase in strength is related to the slow development of an aluminosilicate network enclosing preformed polysilicate chains. A fast condensation of silicate chains occurs during the dissolution of metakaolin in the first 25 h of the ageing process. The subsequent destruction of polymeric silicate chains finally causes the weakening.
AB - The ageing of metakaolin-based geopolymer of special composition (1.2K 2O·Al2O3·4.2SiO 2· 14H2O) has been studied by flexural force measurements, a molybdate analytical method and Fourier transform infrared spectroscopy (FTIR). The results enable new insight into details of the structural development responsible for early strength development between 25 h and 100 h and the unfavorable weakening for ageing above 200 h. In particular the increase in strength is related to the slow development of an aluminosilicate network enclosing preformed polysilicate chains. A fast condensation of silicate chains occurs during the dissolution of metakaolin in the first 25 h of the ageing process. The subsequent destruction of polymeric silicate chains finally causes the weakening.
UR - http://www.scopus.com/inward/record.url?scp=77955583627&partnerID=8YFLogxK
U2 - 10.1002/9780470909836.ch30
DO - 10.1002/9780470909836.ch30
M3 - Conference contribution
AN - SCOPUS:77955583627
SN - 9780470889367
T3 - Ceramic Transactions
SP - 315
EP - 324
BT - Design, Development, and Applications of Engineering Ceramics and Composites - A Collection of Papers Presented at the 8th Pacific Rim Conference on Ceramic and Glass Technology, PACRIM 8
PB - American Ceramic Society
T2 - 8th Pacific Rim Conference on Ceramic and Glass Technology, PACRIM-8
Y2 - 31 May 2009 through 5 June 2009
ER -