Details
| Original language | English |
|---|---|
| Pages (from-to) | 210-218 |
| Number of pages | 9 |
| Journal | Microporous and Mesoporous Materials |
| Volume | 132 |
| Issue number | 1-2 |
| Early online date | 26 Feb 2010 |
| Publication status | Published - Jul 2010 |
Abstract
Tetrahydroborate sodalite nanoparticles were successfully synthesized under low temperature hydrothermal conditions (333 K) from high alkaline aluminosilicate gels and NaBH4 salt. The products were characterized by X-ray powder diffraction, scanning electron microscopy, FTIR spectroscopy and thermogravimetry in comparison with the microcrystalline sample Na8[AlSiO4]6(BH4)2· NaBH4-sodalite of 25 nm average crystal size agglomerated by X-ray amorphous hydrosodalite type phase to bigger particles up to ∼100 nm was observed after a reaction period of 12 h. The sodalite host framework protects the BH4- ions from hydrolysis under open conditions at room temperature. Hydrogen release is detected via nitrate tracer reduction in temperature dependent IR (TIR) experiments. A total conversion of the BH4 groups for the nanocrystalline sodalite sample is reached at 773 K whereas a larger amount of the BH4--units remained stable within the microcrystalline sample under the same conditions. This can be explained by the smaller crystal size and the high amount of inter grown hydrosodalite type phase in the BH4--sodalite nanocrystals compared to the microcrystals. The minor hydrosodalite type phase also present in the microcrystalline sample can be reloaded with water and the main hydrogen release reaction BH4- + 2H2O => 4H2 + BO2- can be continued.
Keywords
- Model for hydride enclathration, Nanocrystalline solids, Synthesis, Tetrahydroborate sodalite, Thermal behaviour
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
- Engineering(all)
- Mechanics of Materials
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In: Microporous and Mesoporous Materials, Vol. 132, No. 1-2, 07.2010, p. 210-218.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Tetrahydroborate sodalite nanocrystals
T2 - Low temperature synthesis and thermally controlled intra-cage reactions for hydrogen release of nano- and micro crystals
AU - Buhl, Josef Christian
AU - Schomborg, Lars
AU - Rüscher, Claus Henning
PY - 2010/7
Y1 - 2010/7
N2 - Tetrahydroborate sodalite nanoparticles were successfully synthesized under low temperature hydrothermal conditions (333 K) from high alkaline aluminosilicate gels and NaBH4 salt. The products were characterized by X-ray powder diffraction, scanning electron microscopy, FTIR spectroscopy and thermogravimetry in comparison with the microcrystalline sample Na8[AlSiO4]6(BH4)2· NaBH4-sodalite of 25 nm average crystal size agglomerated by X-ray amorphous hydrosodalite type phase to bigger particles up to ∼100 nm was observed after a reaction period of 12 h. The sodalite host framework protects the BH4- ions from hydrolysis under open conditions at room temperature. Hydrogen release is detected via nitrate tracer reduction in temperature dependent IR (TIR) experiments. A total conversion of the BH4 groups for the nanocrystalline sodalite sample is reached at 773 K whereas a larger amount of the BH4--units remained stable within the microcrystalline sample under the same conditions. This can be explained by the smaller crystal size and the high amount of inter grown hydrosodalite type phase in the BH4--sodalite nanocrystals compared to the microcrystals. The minor hydrosodalite type phase also present in the microcrystalline sample can be reloaded with water and the main hydrogen release reaction BH4- + 2H2O => 4H2 + BO2- can be continued.
AB - Tetrahydroborate sodalite nanoparticles were successfully synthesized under low temperature hydrothermal conditions (333 K) from high alkaline aluminosilicate gels and NaBH4 salt. The products were characterized by X-ray powder diffraction, scanning electron microscopy, FTIR spectroscopy and thermogravimetry in comparison with the microcrystalline sample Na8[AlSiO4]6(BH4)2· NaBH4-sodalite of 25 nm average crystal size agglomerated by X-ray amorphous hydrosodalite type phase to bigger particles up to ∼100 nm was observed after a reaction period of 12 h. The sodalite host framework protects the BH4- ions from hydrolysis under open conditions at room temperature. Hydrogen release is detected via nitrate tracer reduction in temperature dependent IR (TIR) experiments. A total conversion of the BH4 groups for the nanocrystalline sodalite sample is reached at 773 K whereas a larger amount of the BH4--units remained stable within the microcrystalline sample under the same conditions. This can be explained by the smaller crystal size and the high amount of inter grown hydrosodalite type phase in the BH4--sodalite nanocrystals compared to the microcrystals. The minor hydrosodalite type phase also present in the microcrystalline sample can be reloaded with water and the main hydrogen release reaction BH4- + 2H2O => 4H2 + BO2- can be continued.
KW - Model for hydride enclathration
KW - Nanocrystalline solids
KW - Synthesis
KW - Tetrahydroborate sodalite
KW - Thermal behaviour
UR - http://www.scopus.com/inward/record.url?scp=77950339838&partnerID=8YFLogxK
U2 - 10.1016/j.micromeso.2010.02.022
DO - 10.1016/j.micromeso.2010.02.022
M3 - Article
AN - SCOPUS:77950339838
VL - 132
SP - 210
EP - 218
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
IS - 1-2
ER -