Details
| Original language | English |
|---|---|
| Article number | e202200208 |
| Number of pages | 30 |
| Journal | The chemical record |
| Volume | 23 |
| Issue number | 1 |
| Publication status | Published - 19 Jan 2023 |
Abstract
This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.
Keywords
- Cycloaddition-retroelectrocyclization, Photothermal Therapy, Solar Cells, Tetracyanoethylene
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Chemical Engineering(all)
- General Chemical Engineering
- Materials Science(all)
- Materials Chemistry
Sustainable Development Goals
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In: The chemical record, Vol. 23, No. 1, e202200208, 19.01.2023.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Tetracyanobutadiene Bridged Push-Pull Chromophores
T2 - Development of New Generation Optoelectronic Materials
AU - Patil, Yuvraj
AU - Butenschön, Holger
AU - Misra, Rajneesh
N1 - Funding Information: We thank the and SERB (Project No. CRG/2018/000032), New Delhi, and DAAD (Leibniz University Hannover and IIT Indore project). R. M. thanks the Alexander von Humboldt Foundation for a research fellowship. Open Access funding enabled and organized by Projekt DEAL. New Passage to India
PY - 2023/1/19
Y1 - 2023/1/19
N2 - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.
AB - This review describes the design strategies used for the synthesis of various tetracyanobutadiene bridged donor-acceptor molecular architectures by a click type [2+2] cycloaddition-retroelectrocyclization (CA-RE) reaction sequence. The photophysical and electrochemical properties of the tetracyanobutadiene bridged molecular architectures based on various moieties including diketopyrrolopyrrole, isoindigo, benzothiadiazole, pyrene, pyrazabole, truxene, boron dipyrromethene (BODIPY), phenothiazine, triphenylamine, thiazole and bisthiazole are summarized. Further, we discuss some important applications of the tetracyanobutadiene bridged derivatives in dye sensitized solar cells, bulk heterojunction solar cells and photothermal cancer therapy.
KW - Cycloaddition-retroelectrocyclization
KW - Photothermal Therapy
KW - Solar Cells
KW - Tetracyanoethylene
UR - http://www.scopus.com/inward/record.url?scp=85139475496&partnerID=8YFLogxK
U2 - 10.1002/tcr.202200208
DO - 10.1002/tcr.202200208
M3 - Review article
AN - SCOPUS:85139475496
VL - 23
JO - The chemical record
JF - The chemical record
SN - 1527-8999
IS - 1
M1 - e202200208
ER -