Details
| Original language | English |
|---|---|
| Pages (from-to) | 1177-1179 |
| Number of pages | 3 |
| Journal | Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences |
| Volume | 59 |
| Issue number | 10 |
| Publication status | Published - Oct 2004 |
Abstract
The reaction of β-himachalene with dichlorocarbene followed by ruthenium catalyzed oxidation under Sharpless conditions yields 8,8-dichloro-3,3,7-trimethyl-1(3-oxobutyl)bicyclo[5.1.0]octane-2-carboxylic acid (3). The absolute configuration was determined crystallographically to be (1S, 2R, 7R).
Keywords
- Absolute Configuration, Cyclopropanation, Himachalene, Ruthenium Oxidation
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
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In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 59, No. 10, 10.2004, p. 1177-1179.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Synthesis, structure, and absolute configuration of a new cyclopropanic compound derived from the sesquiterpene β-himachalene
AU - Ziyat, Hossni
AU - El Houssame, Soufiane
AU - Ait Ali, Mustapha
AU - Ait Itto, My Youssef
AU - Karim, Abdellah
AU - Wartchow, Rudolf
AU - Butenschön, Holger
N1 - Funding information: This work was kindly supported by the German Academic Exchange Service (DAAD) by a fellowship for Soufiane El Houssame.
PY - 2004/10
Y1 - 2004/10
N2 - The reaction of β-himachalene with dichlorocarbene followed by ruthenium catalyzed oxidation under Sharpless conditions yields 8,8-dichloro-3,3,7-trimethyl-1(3-oxobutyl)bicyclo[5.1.0]octane-2-carboxylic acid (3). The absolute configuration was determined crystallographically to be (1S, 2R, 7R).
AB - The reaction of β-himachalene with dichlorocarbene followed by ruthenium catalyzed oxidation under Sharpless conditions yields 8,8-dichloro-3,3,7-trimethyl-1(3-oxobutyl)bicyclo[5.1.0]octane-2-carboxylic acid (3). The absolute configuration was determined crystallographically to be (1S, 2R, 7R).
KW - Absolute Configuration
KW - Cyclopropanation
KW - Himachalene
KW - Ruthenium Oxidation
UR - http://www.scopus.com/inward/record.url?scp=8744233778&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:8744233778
VL - 59
SP - 1177
EP - 1179
JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
SN - 0932-0776
IS - 10
ER -