Details
| Original language | English |
|---|---|
| Pages (from-to) | 4885-4898 |
| Number of pages | 14 |
| Journal | Journal of Environmental Chemical Engineering |
| Volume | 6 |
| Issue number | 4 |
| Early online date | 17 Jul 2018 |
| Publication status | Published - Aug 2018 |
Abstract
In this study, one-step hydrothermal route was adopted to synthesize Co doped ZnWO 4 nanorods for efficient removal of inorganic and organic pollutants. The samples were carefully characterized by standard analytical techniques to investigate the optical, morphological and structural properties of the prepared samples. TEM analysis shows the rod-like morphology with average diameter of 60-100 nm. The activity of prepared samples was evaluated by studying the photodegradation of RhB, MB, MO, photo-reduction of Cr(VI) and simultaneous photo-oxidation and reduction of binary mixture of RhB and Cr(VI) under UV-light source. Among the series of prepared samples, 1 mol% Co doped ZnWO 4 (1 Co-ZW) showed improved photocatalytic activity in both single and mixed pollutant solutions. In the single dye solutions, a maximum degradation of 94.4%, 95% and 86.4% was obtained for RhB, MB and MO, respectively under 120 min of irradiation using 1 Co-ZW. Moreover, a maximum efficiency of 97.8% and 99% was achieved by 1 Co-ZW for the oxidation of RhB and reduction of Cr(VI), respectively from the binary (RhB + Cr(VI)) solution under the same irradiation time. The degradation results indicate that simultaneous degradation of pollutants is more prominent than that of the individual ones. The reactive species involved in the removal of RhB and Cr(VI) was determined by different scavengers and a probable mechanism for enhanced photocatalytic activity has been proposed accordingly. The present work offers an innovative approach towards the design and development of reusable catalysts to remove both organic and inorganic pollutants present in wastewater using UV-light source.
Keywords
- Co-doped ZnWO nanorod, Oxidation of RhB and synergistic effect, Photoreduction of Cr(VI)
ASJC Scopus subject areas
- Chemical Engineering(all)
- Chemical Engineering (miscellaneous)
- Environmental Science(all)
- Waste Management and Disposal
- Environmental Science(all)
- Pollution
- Chemical Engineering(all)
- Process Chemistry and Technology
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In: Journal of Environmental Chemical Engineering, Vol. 6, No. 4, 08.2018, p. 4885-4898.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Synthesis of Co doped ZnWO4 for simultaneous oxidation of RhB and reduction of Cr(VI) under UV-light irradiation
AU - Alam, U.
AU - Khan, A.
AU - Bahnemann, D.
AU - Muneer, M.
N1 - © 2018 Elsevier Ltd. All rights reserved.
PY - 2018/8
Y1 - 2018/8
N2 - In this study, one-step hydrothermal route was adopted to synthesize Co doped ZnWO 4 nanorods for efficient removal of inorganic and organic pollutants. The samples were carefully characterized by standard analytical techniques to investigate the optical, morphological and structural properties of the prepared samples. TEM analysis shows the rod-like morphology with average diameter of 60-100 nm. The activity of prepared samples was evaluated by studying the photodegradation of RhB, MB, MO, photo-reduction of Cr(VI) and simultaneous photo-oxidation and reduction of binary mixture of RhB and Cr(VI) under UV-light source. Among the series of prepared samples, 1 mol% Co doped ZnWO 4 (1 Co-ZW) showed improved photocatalytic activity in both single and mixed pollutant solutions. In the single dye solutions, a maximum degradation of 94.4%, 95% and 86.4% was obtained for RhB, MB and MO, respectively under 120 min of irradiation using 1 Co-ZW. Moreover, a maximum efficiency of 97.8% and 99% was achieved by 1 Co-ZW for the oxidation of RhB and reduction of Cr(VI), respectively from the binary (RhB + Cr(VI)) solution under the same irradiation time. The degradation results indicate that simultaneous degradation of pollutants is more prominent than that of the individual ones. The reactive species involved in the removal of RhB and Cr(VI) was determined by different scavengers and a probable mechanism for enhanced photocatalytic activity has been proposed accordingly. The present work offers an innovative approach towards the design and development of reusable catalysts to remove both organic and inorganic pollutants present in wastewater using UV-light source.
AB - In this study, one-step hydrothermal route was adopted to synthesize Co doped ZnWO 4 nanorods for efficient removal of inorganic and organic pollutants. The samples were carefully characterized by standard analytical techniques to investigate the optical, morphological and structural properties of the prepared samples. TEM analysis shows the rod-like morphology with average diameter of 60-100 nm. The activity of prepared samples was evaluated by studying the photodegradation of RhB, MB, MO, photo-reduction of Cr(VI) and simultaneous photo-oxidation and reduction of binary mixture of RhB and Cr(VI) under UV-light source. Among the series of prepared samples, 1 mol% Co doped ZnWO 4 (1 Co-ZW) showed improved photocatalytic activity in both single and mixed pollutant solutions. In the single dye solutions, a maximum degradation of 94.4%, 95% and 86.4% was obtained for RhB, MB and MO, respectively under 120 min of irradiation using 1 Co-ZW. Moreover, a maximum efficiency of 97.8% and 99% was achieved by 1 Co-ZW for the oxidation of RhB and reduction of Cr(VI), respectively from the binary (RhB + Cr(VI)) solution under the same irradiation time. The degradation results indicate that simultaneous degradation of pollutants is more prominent than that of the individual ones. The reactive species involved in the removal of RhB and Cr(VI) was determined by different scavengers and a probable mechanism for enhanced photocatalytic activity has been proposed accordingly. The present work offers an innovative approach towards the design and development of reusable catalysts to remove both organic and inorganic pollutants present in wastewater using UV-light source.
KW - Co-doped ZnWO nanorod
KW - Oxidation of RhB and synergistic effect
KW - Photoreduction of Cr(VI)
UR - http://www.scopus.com/inward/record.url?scp=85050390414&partnerID=8YFLogxK
U2 - 10.1016/j.jece.2018.07.028
DO - 10.1016/j.jece.2018.07.028
M3 - Article
VL - 6
SP - 4885
EP - 4898
JO - Journal of Environmental Chemical Engineering
JF - Journal of Environmental Chemical Engineering
IS - 4
ER -