Details
| Original language | English |
|---|---|
| Pages (from-to) | 1155-1157 |
| Number of pages | 3 |
| Journal | New journal of chemistry |
| Volume | 22 |
| Issue number | 11 |
| Publication status | Published - 1998 |
Abstract
μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- Materials Chemistry
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In: New journal of chemistry, Vol. 22, No. 11, 1998, p. 1155-1157.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Synthesis and characterization of a tricobalt cluster with μ3 tert-butylcarbyne and PSe ligands
AU - Foerstner, Jan
AU - Wartchow, Rudolf
AU - Butenschön, Holger
PY - 1998
Y1 - 1998
N2 - μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.
AB - μ3-Phosphido cluster 2, which is readily accessible from the cobalt chelate 1 by treatment with tert-butylphosphaethyne, reacts with red selenium to give the moderately air- and light-sensitive tetraselenide 4 with μ3 tert-butylcarbyn and μ3 PSe ligands in 48% yield. The crystal structure of 4 is reported and compared to those of closely related clusters.
UR - http://www.scopus.com/inward/record.url?scp=0001688019&partnerID=8YFLogxK
U2 - 10.1039/a803784a
DO - 10.1039/a803784a
M3 - Article
AN - SCOPUS:0001688019
VL - 22
SP - 1155
EP - 1157
JO - New journal of chemistry
JF - New journal of chemistry
SN - 1144-0546
IS - 11
ER -