Details
| Translated title of the contribution | Nachhaltige Konzepte in der Olefinmetathese |
|---|---|
| Original language | English |
| Pages (from-to) | 6786-6801 |
| Number of pages | 16 |
| Journal | Angewandte Chemie |
| Volume | 46 |
| Issue number | 36 |
| Publication status | Published - 4 Sept 2007 |
Abstract
Ruthenium-catalyzed olefin metathesis reactions represent an attractive and powerful transformation for the formation of new carbon - carbon double bonds. This area is now quite familiar to most chemists as numerous catalysts are available that enable a plethora of olefin metathesis reactions. Nevertheless, with the exception of uses in polymerization reactions, only a limited number of industrial processes use olefin metathesis. This is mainly due to difficulties associated with removing ruthenium from the final products. In this context, a number of studies have been carried out to develop procedures for the removal of the catalyst or the products of catalyst decomposition, however, none are universally attractive so far. This situation has resulted in tremendous activity in the area dealing with supported or tagged versions of homogeneous catalysts. This Review summarizes the numerous studies focused on developing cleaner ruthenium-catalyzed metathesis processes.
Keywords
- Olefin metathesis, Purification processes, Ruthenium, Supported catalysts, Sustainable chemistry
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
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In: Angewandte Chemie , Vol. 46, No. 36, 04.09.2007, p. 6786-6801.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Sustainable concepts in olefin metathesis
AU - Clavier, Hervé
AU - Grela, Karol
AU - Kirschning, Andreas
AU - Mauduit, Marc
AU - Nolan, Steven P.
PY - 2007/9/4
Y1 - 2007/9/4
N2 - Ruthenium-catalyzed olefin metathesis reactions represent an attractive and powerful transformation for the formation of new carbon - carbon double bonds. This area is now quite familiar to most chemists as numerous catalysts are available that enable a plethora of olefin metathesis reactions. Nevertheless, with the exception of uses in polymerization reactions, only a limited number of industrial processes use olefin metathesis. This is mainly due to difficulties associated with removing ruthenium from the final products. In this context, a number of studies have been carried out to develop procedures for the removal of the catalyst or the products of catalyst decomposition, however, none are universally attractive so far. This situation has resulted in tremendous activity in the area dealing with supported or tagged versions of homogeneous catalysts. This Review summarizes the numerous studies focused on developing cleaner ruthenium-catalyzed metathesis processes.
AB - Ruthenium-catalyzed olefin metathesis reactions represent an attractive and powerful transformation for the formation of new carbon - carbon double bonds. This area is now quite familiar to most chemists as numerous catalysts are available that enable a plethora of olefin metathesis reactions. Nevertheless, with the exception of uses in polymerization reactions, only a limited number of industrial processes use olefin metathesis. This is mainly due to difficulties associated with removing ruthenium from the final products. In this context, a number of studies have been carried out to develop procedures for the removal of the catalyst or the products of catalyst decomposition, however, none are universally attractive so far. This situation has resulted in tremendous activity in the area dealing with supported or tagged versions of homogeneous catalysts. This Review summarizes the numerous studies focused on developing cleaner ruthenium-catalyzed metathesis processes.
KW - Olefin metathesis
KW - Purification processes
KW - Ruthenium
KW - Supported catalysts
KW - Sustainable chemistry
UR - http://www.scopus.com/inward/record.url?scp=34548728077&partnerID=8YFLogxK
U2 - 10.1002/anie.200605099
DO - 10.1002/anie.200605099
M3 - Review article
C2 - 17640026
AN - SCOPUS:34548728077
VL - 46
SP - 6786
EP - 6801
JO - Angewandte Chemie
JF - Angewandte Chemie
SN - 1433-7851
IS - 36
ER -