Surface passivation of high-efficiency silicon solar cells by atomic-layer-deposited Al2O3

Research output: Contribution to journalArticleResearchpeer review

Authors

  • J. Schmidt
  • A. Merkle
  • R. Brendel
  • B. Hoex
  • M. C.M. Van De Sanden
  • W. M.M. Kessels

External Research Organisations

  • Institute for Solar Energy Research (ISFH)
  • Eindhoven University of Technology (TU/e)
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Details

Original languageEnglish
Pages (from-to)461-466
Number of pages6
JournalProgress in Photovoltaics: Research and Applications
Volume16
Issue number6
Early online date3 Mar 2008
Publication statusPublished - Sept 2008
Externally publishedYes

Abstract

Atomic-layer-deposited aluminium oxide (Al2O3) is applied as rear-surface-passivating dielectric layer to passivated emitter and rear cell (PERC)-type crystalline silicon (c-Si) solar cells. The excellent passivation of low-resistivity p-type silicon by the negative-charge-dielectric Al2O3 is confirmed on the device level by an independently confirmed energy conversion efficiency of 20 6%. The best results are obtained for a stack consisting of a 30 nm Al2O3 film covered by a 200 nm plasma-enhanced-chemical-vapour-deposited silicon oxide (SiOx) layer, resulting in a rear surface recombination velocity (SRV) of 70cm/s. Comparable results are obtained for a 130 nm single-layer of Al 2O3, resulting in a rear SRV of 90 cm/s.

Keywords

    Aluminium oxide, Crystalline silicon solar cells, High-efficiency cells, Surface passivation

ASJC Scopus subject areas

Sustainable Development Goals

Cite this

Surface passivation of high-efficiency silicon solar cells by atomic-layer-deposited Al2O3. / Schmidt, J.; Merkle, A.; Brendel, R. et al.
In: Progress in Photovoltaics: Research and Applications, Vol. 16, No. 6, 09.2008, p. 461-466.

Research output: Contribution to journalArticleResearchpeer review

Schmidt J, Merkle A, Brendel R, Hoex B, Van De Sanden MCM, Kessels WMM. Surface passivation of high-efficiency silicon solar cells by atomic-layer-deposited Al2O3. Progress in Photovoltaics: Research and Applications. 2008 Sept;16(6):461-466. Epub 2008 Mar 3. doi: 10.1002/pip.823
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abstract = "Atomic-layer-deposited aluminium oxide (Al2O3) is applied as rear-surface-passivating dielectric layer to passivated emitter and rear cell (PERC)-type crystalline silicon (c-Si) solar cells. The excellent passivation of low-resistivity p-type silicon by the negative-charge-dielectric Al2O3 is confirmed on the device level by an independently confirmed energy conversion efficiency of 20 6%. The best results are obtained for a stack consisting of a 30 nm Al2O3 film covered by a 200 nm plasma-enhanced-chemical-vapour-deposited silicon oxide (SiOx) layer, resulting in a rear surface recombination velocity (SRV) of 70cm/s. Comparable results are obtained for a 130 nm single-layer of Al 2O3, resulting in a rear SRV of 90 cm/s.",
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AU - Schmidt, J.

AU - Merkle, A.

AU - Brendel, R.

AU - Hoex, B.

AU - Van De Sanden, M. C.M.

AU - Kessels, W. M.M.

N1 - Funding Information: We gratefullyacknowledge the financial support provided by theGerman State of Lower Saxony and the NetherlandsTechnology Foundation STW.

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AB - Atomic-layer-deposited aluminium oxide (Al2O3) is applied as rear-surface-passivating dielectric layer to passivated emitter and rear cell (PERC)-type crystalline silicon (c-Si) solar cells. The excellent passivation of low-resistivity p-type silicon by the negative-charge-dielectric Al2O3 is confirmed on the device level by an independently confirmed energy conversion efficiency of 20 6%. The best results are obtained for a stack consisting of a 30 nm Al2O3 film covered by a 200 nm plasma-enhanced-chemical-vapour-deposited silicon oxide (SiOx) layer, resulting in a rear surface recombination velocity (SRV) of 70cm/s. Comparable results are obtained for a 130 nm single-layer of Al 2O3, resulting in a rear SRV of 90 cm/s.

KW - Aluminium oxide

KW - Crystalline silicon solar cells

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