Details
| Original language | English |
|---|---|
| Pages (from-to) | 1942-1946 |
| Number of pages | 5 |
| Journal | SYNLETT |
| Volume | 31 |
| Issue number | 19 |
| Publication status | Published - 27 Oct 2020 |
Abstract
Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.
Keywords
- Claisen rearrangement, flow chemistry, fluorobenzenes, inductive heating, supercritical water
ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
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In: SYNLETT, Vol. 31, No. 19, 27.10.2020, p. 1942-1946.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Subsupercritical Water Generated by Inductive Heating Inside Flow Reactors Facilitates the Claisen Rearrangement
AU - Oltmanns, Mona
AU - Kirschning, Andreas
N1 - Funding Information: This work was supported in part by the Symrise AG, Holzminden, Germany.()
PY - 2020/10/27
Y1 - 2020/10/27
N2 - Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.
AB - Claisen rearrangement of electron-deficient O-allylated phenols, including fluorine-modified phenols, is facilitated in aqueous media at high temperatures and pressures under flow conditions, as opposed to organic solvents. The O-allylation of phenols can be coupled with the Claisen rearrangement in an integrated flow system.
KW - Claisen rearrangement
KW - flow chemistry
KW - fluorobenzenes
KW - inductive heating
KW - supercritical water
UR - http://www.scopus.com/inward/record.url?scp=85095838695&partnerID=8YFLogxK
U2 - 10.1055/s-0040-1705945
DO - 10.1055/s-0040-1705945
M3 - Article
AN - SCOPUS:85095838695
VL - 31
SP - 1942
EP - 1946
JO - SYNLETT
JF - SYNLETT
SN - 0936-5214
IS - 19
ER -