Details
| Original language | English |
|---|---|
| Pages (from-to) | 429-432 |
| Number of pages | 4 |
| Journal | Synlett |
| Issue number | 3 |
| Publication status | Published - 21 Jan 2009 |
Abstract
The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
Keywords
- Bissilyl ketones, Brook rearrangement, Formyl anion, Organolithium species, Silyl migration
ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
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In: Synlett, No. 3, 21.01.2009, p. 429-432.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Studies on the 1,2-brook rearrangement of bissilyl ketones
AU - Kirschning, Andreas
AU - Luiken, Silke
AU - Migliorini, Antonella
AU - Loreto, Maria Antonietta
AU - Vogt, Monika
PY - 2009/1/21
Y1 - 2009/1/21
N2 - The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
AB - The first 1,2-Brook rearrangements with bis(dimethylphenylsilyl) ketone, initiated after addition of different C- and S-nucleophiles, are described. The resulting, newly formed carbanion can be trapped with electrophiles thus paving the way for utilizing bissilyl ketones as formyl dianion equivalents in the future.
KW - Bissilyl ketones
KW - Brook rearrangement
KW - Formyl anion
KW - Organolithium species
KW - Silyl migration
UR - http://www.scopus.com/inward/record.url?scp=62249152542&partnerID=8YFLogxK
U2 - 10.1055/s-0028-1087535
DO - 10.1055/s-0028-1087535
M3 - Article
AN - SCOPUS:62249152542
SP - 429
EP - 432
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 3
ER -