Details
| Original language | English |
|---|---|
| Pages (from-to) | 223-230 |
| Number of pages | 8 |
| Journal | Synthetic metals |
| Volume | 34 |
| Issue number | 1-3 |
| Publication status | Published - 1989 |
| Externally published | Yes |
Abstract
An overview over the structural characteristics of the in-plane structures of metal chloride GICs+ is given. After a classification according to the topology of the structure of the intercalate layer (i. e. according to whether the guest-guest interactions are strong in zero, one or two dimensions) is proposed, several special questions are treated. These include the influence of the structure of the pristine chloride on the structure of the intercalated chloride, the variability of the in-plane arrangement as a function of the preparation conditions and of temperature of pressure and the structural effects of the charge, that is transferred from graphite to the intercalate during the intercalation reaction. A very interesting feature, the orientational locking of intercalate lattices which are incommensurate with respect to the graphite in-plane lattice, is addressed at the end of the paper.
ASJC Scopus subject areas
- Materials Science(all)
- Electronic, Optical and Magnetic Materials
- Physics and Astronomy(all)
- Condensed Matter Physics
- Engineering(all)
- Mechanics of Materials
- Engineering(all)
- Mechanical Engineering
- Materials Science(all)
- Metals and Alloys
- Materials Science(all)
- Materials Chemistry
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In: Synthetic metals, Vol. 34, No. 1-3, 1989, p. 223-230.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Structural characteristics of the graphite intercalation compounds of metal chlorides
AU - Behrens, P.
AU - Metz, W.
PY - 1989
Y1 - 1989
N2 - An overview over the structural characteristics of the in-plane structures of metal chloride GICs+ is given. After a classification according to the topology of the structure of the intercalate layer (i. e. according to whether the guest-guest interactions are strong in zero, one or two dimensions) is proposed, several special questions are treated. These include the influence of the structure of the pristine chloride on the structure of the intercalated chloride, the variability of the in-plane arrangement as a function of the preparation conditions and of temperature of pressure and the structural effects of the charge, that is transferred from graphite to the intercalate during the intercalation reaction. A very interesting feature, the orientational locking of intercalate lattices which are incommensurate with respect to the graphite in-plane lattice, is addressed at the end of the paper.
AB - An overview over the structural characteristics of the in-plane structures of metal chloride GICs+ is given. After a classification according to the topology of the structure of the intercalate layer (i. e. according to whether the guest-guest interactions are strong in zero, one or two dimensions) is proposed, several special questions are treated. These include the influence of the structure of the pristine chloride on the structure of the intercalated chloride, the variability of the in-plane arrangement as a function of the preparation conditions and of temperature of pressure and the structural effects of the charge, that is transferred from graphite to the intercalate during the intercalation reaction. A very interesting feature, the orientational locking of intercalate lattices which are incommensurate with respect to the graphite in-plane lattice, is addressed at the end of the paper.
UR - http://www.scopus.com/inward/record.url?scp=0024933294&partnerID=8YFLogxK
U2 - 10.1016/0379-6779(89)90389-5
DO - 10.1016/0379-6779(89)90389-5
M3 - Article
AN - SCOPUS:0024933294
VL - 34
SP - 223
EP - 230
JO - Synthetic metals
JF - Synthetic metals
SN - 0379-6779
IS - 1-3
ER -