Details
| Original language | English |
|---|---|
| Pages (from-to) | 833-836 |
| Number of pages | 4 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 348 |
| Issue number | 7-8 |
| Publication status | Published - 5 May 2006 |
Abstract
The hydrosilylation of alkynes is catalyzed by the di-tert- butylphosphanylethylcyclopentadienyl-cobalt chelate 1. While the reaction of internal alkynes exclusively affords syn hydrosilylation products with triethylsilane, the reaction with triethoxysilane shows predominant anti stereoselectivity. Reactions of terminal alkynes are less selective with triethylsilane and result in cyclotrimerization when triethoxysilane is used.
Keywords
- Alkynes, Cobalt, Hydrosilylation, P ligands, Triethoxysilane, Triethylsilane
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Advanced Synthesis and Catalysis, Vol. 348, No. 7-8, 05.05.2006, p. 833-836.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Stereodivergent Formation of Alkenylsilanes
T2 - syn or anti Hydrosilylation of alkynes catalyzed by a cyclopentadienylcobalt(I) chelate bearing a pendant phosphane tether
AU - Yong, Li
AU - Kirleis, Karin
AU - Butenschön, Holger
PY - 2006/5/5
Y1 - 2006/5/5
N2 - The hydrosilylation of alkynes is catalyzed by the di-tert- butylphosphanylethylcyclopentadienyl-cobalt chelate 1. While the reaction of internal alkynes exclusively affords syn hydrosilylation products with triethylsilane, the reaction with triethoxysilane shows predominant anti stereoselectivity. Reactions of terminal alkynes are less selective with triethylsilane and result in cyclotrimerization when triethoxysilane is used.
AB - The hydrosilylation of alkynes is catalyzed by the di-tert- butylphosphanylethylcyclopentadienyl-cobalt chelate 1. While the reaction of internal alkynes exclusively affords syn hydrosilylation products with triethylsilane, the reaction with triethoxysilane shows predominant anti stereoselectivity. Reactions of terminal alkynes are less selective with triethylsilane and result in cyclotrimerization when triethoxysilane is used.
KW - Alkynes
KW - Cobalt
KW - Hydrosilylation
KW - P ligands
KW - Triethoxysilane
KW - Triethylsilane
UR - http://www.scopus.com/inward/record.url?scp=33744804798&partnerID=8YFLogxK
U2 - 10.1002/adsc.200606028
DO - 10.1002/adsc.200606028
M3 - Article
AN - SCOPUS:33744804798
VL - 348
SP - 833
EP - 836
JO - Advanced Synthesis and Catalysis
JF - Advanced Synthesis and Catalysis
SN - 1615-4150
IS - 7-8
ER -