Details
| Original language | English |
|---|---|
| Pages (from-to) | 14008-14018 |
| Number of pages | 11 |
| Journal | Dalton transactions |
| Volume | 45 |
| Issue number | 36 |
| Publication status | Published - 11 Aug 2016 |
Abstract
Electromagnetic stimuli of spin crossover compounds restricted to UV-vis light irradiation for many years could be recently extended to X-ray excitation. This review covers a large variety of light-induced effects, as well as recent analogues stimulated by X-ray irradiation which have not yet been reviewed. The focus is also on multistable multinuclear spin crossover compounds which are the subject of lively discussions within the spin crossover community. Their spin transition often occurs incompletely and with different switching mechanisms. In this review, we recall a predicted sequential switching induced thermally as well as a concerted stimulation mechanism by light irradiation for these interesting multifunctional materials.
ASJC Scopus subject areas
- Chemistry(all)
- Inorganic Chemistry
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In: Dalton transactions, Vol. 45, No. 36, 11.08.2016, p. 14008-14018.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Spin state switching of metal complexes by visible light or hard X-rays
AU - Unruh, Daniel
AU - Homenya, Patrick
AU - Kumar, Manish
AU - Sindelar, Ralf
AU - Garcia, Yann
AU - Renz, Franz
PY - 2016/8/11
Y1 - 2016/8/11
N2 - Electromagnetic stimuli of spin crossover compounds restricted to UV-vis light irradiation for many years could be recently extended to X-ray excitation. This review covers a large variety of light-induced effects, as well as recent analogues stimulated by X-ray irradiation which have not yet been reviewed. The focus is also on multistable multinuclear spin crossover compounds which are the subject of lively discussions within the spin crossover community. Their spin transition often occurs incompletely and with different switching mechanisms. In this review, we recall a predicted sequential switching induced thermally as well as a concerted stimulation mechanism by light irradiation for these interesting multifunctional materials.
AB - Electromagnetic stimuli of spin crossover compounds restricted to UV-vis light irradiation for many years could be recently extended to X-ray excitation. This review covers a large variety of light-induced effects, as well as recent analogues stimulated by X-ray irradiation which have not yet been reviewed. The focus is also on multistable multinuclear spin crossover compounds which are the subject of lively discussions within the spin crossover community. Their spin transition often occurs incompletely and with different switching mechanisms. In this review, we recall a predicted sequential switching induced thermally as well as a concerted stimulation mechanism by light irradiation for these interesting multifunctional materials.
UR - http://www.scopus.com/inward/record.url?scp=84987838379&partnerID=8YFLogxK
U2 - 10.1039/c6dt01745b
DO - 10.1039/c6dt01745b
M3 - Review article
AN - SCOPUS:84987838379
VL - 45
SP - 14008
EP - 14018
JO - Dalton transactions
JF - Dalton transactions
SN - 1477-9226
IS - 36
ER -