Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Esther Breuning
  • Mario Ruben
  • Jean Marie Lehn
  • Franz Renz
  • Yann Garcia
  • Vadim Ksenofontov
  • Philipp Gütlich
  • Elina Wegelius
  • Kari Rissanen

Research Organisations

External Research Organisations

  • Institut de Science et d’Ingénierie Supramoléculaires
  • Johannes Gutenberg University Mainz
  • University of Jyvaskyla
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Details

Original languageEnglish
Pages (from-to)2504-2507
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number14
Publication statusPublished - 17 Jul 2000

Abstract

A multiplex electronic switch on the molecular level has been realized by using a tetranuclear Fe(II) complex of the [2 x 2] grid type. The four metal ions can be switched stepwise between their high-spin and low-spin states by temperature, pressure, and light, thus representing a triple level, triple switch system as illustrated in the picture.

Keywords

    Iron, Magnetic properties, Moessbauer spectroscopy, Spin crossover, Supramolecular chemistry

ASJC Scopus subject areas

Cite this

Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light. / Breuning, Esther; Ruben, Mario; Lehn, Jean Marie et al.
In: Angewandte Chemie - International Edition, Vol. 39, No. 14, 17.07.2000, p. 2504-2507.

Research output: Contribution to journalArticleResearchpeer review

Breuning, E, Ruben, M, Lehn, JM, Renz, F, Garcia, Y, Ksenofontov, V, Gütlich, P, Wegelius, E & Rissanen, K 2000, 'Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light', Angewandte Chemie - International Edition, vol. 39, no. 14, pp. 2504-2507. https://doi.org/10.1002/1521-3773(20000717)39:14<2504::AID-ANIE2504>3.0.CO;2-B
Breuning, E., Ruben, M., Lehn, J. M., Renz, F., Garcia, Y., Ksenofontov, V., Gütlich, P., Wegelius, E., & Rissanen, K. (2000). Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light. Angewandte Chemie - International Edition, 39(14), 2504-2507. https://doi.org/10.1002/1521-3773(20000717)39:14<2504::AID-ANIE2504>3.0.CO;2-B
Breuning E, Ruben M, Lehn JM, Renz F, Garcia Y, Ksenofontov V et al. Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light. Angewandte Chemie - International Edition. 2000 Jul 17;39(14):2504-2507. doi: 10.1002/1521-3773(20000717)39:14<2504::AID-ANIE2504>3.0.CO;2-B
Breuning, Esther ; Ruben, Mario ; Lehn, Jean Marie et al. / Spin crossover in a supramolecular Fe4(II) [2 x 2] grid triggered by temparature, pressure, and light. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 14. pp. 2504-2507.
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