Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Max Wilke
  • François Farges
  • Georg M. Partzsch
  • Christian Schmidt
  • Harald Behrens

Research Organisations

External Research Organisations

  • University of Potsdam
  • Université Paris-Est Créteil Val-de-Marne (UPEC)
  • Stanford University
  • Heidelberg University
  • Helmholtz Centre Potsdam - German Research Centre for Geosciences (GFZ)
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Details

Original languageEnglish
Pages (from-to)44-56
Number of pages13
JournalAmerican mineralogist
Volume92
Issue number1
Publication statusPublished - 1 Jan 2007

Abstract

In-situ X-ray absorption spectroscopy at the Fe K-edge was used to characterize the local structural environment of Fe2+ and Fe3+ in silicate melts at high temperature (up to 1050 °C) in comparison to their quenched glassy analog at room temperature. Measurements were performed on binary alkali-silicate compositions and on haplogranitic compositions, which were doped with about 5 wt% Fe2O3. Changes in the structural environment of Fe were evaluated by analyzing both the pre-edge feature and the first maximum of the EXAFS of the spectra. In most cases, the spectra collected at high temperature differed from those of the quenched samples. At reducing conditions, the melts showed slightly higher amounts of low-coordinated Fe2+ than their glassy counterparts. This finding is consistent with results of earlier studies (e.g., Jackson et al. 1993), but the observed change in speciation is smaller than reported by these authors. At oxidizing conditions, glasses and melts displayed a more heterogeneous behavior. The spectra of alkali-silicate compositions indicate higher amounts of low-coordinated Fe3+ in the melt, whereas no significant difference between melt and glass was observed for Fe3+ in haplogranitic compositions, even if the latter are peralkaline. The amount of non-bridging O atoms in the glass/ melt system appears to play an important role particularly for Fe3+. However, more complex relationships between Fe and other structural components, especially Al, are possible.

Keywords

    Fe in silicate melts, Fe K-edge, Glass properties, High-temperature studies, Melt properties, XAS (XAFS, XANES)

ASJC Scopus subject areas

Cite this

Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy. / Wilke, Max; Farges, François; Partzsch, Georg M. et al.
In: American mineralogist, Vol. 92, No. 1, 01.01.2007, p. 44-56.

Research output: Contribution to journalArticleResearchpeer review

Wilke, M, Farges, F, Partzsch, GM, Schmidt, C & Behrens, H 2007, 'Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy', American mineralogist, vol. 92, no. 1, pp. 44-56. https://doi.org/10.2138/am.2007.1976
Wilke, M., Farges, F., Partzsch, G. M., Schmidt, C., & Behrens, H. (2007). Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy. American mineralogist, 92(1), 44-56. https://doi.org/10.2138/am.2007.1976
Wilke M, Farges F, Partzsch GM, Schmidt C, Behrens H. Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy. American mineralogist. 2007 Jan 1;92(1):44-56. doi: 10.2138/am.2007.1976
Wilke, Max ; Farges, François ; Partzsch, Georg M. et al. / Speciation of Fe in silicate glasses and melts by in-situ XANES spectroscopy. In: American mineralogist. 2007 ; Vol. 92, No. 1. pp. 44-56.
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