Details
| Original language | English |
|---|---|
| Pages (from-to) | 699-705 |
| Number of pages | 7 |
| Journal | SOLID STATE IONICS |
| Volume | 136-137 |
| Publication status | Published - 2 Nov 2000 |
Abstract
Pt/YSZ electrodes prepared from platinum (Pt) and yttria-stabilized zirconia (YSZ) can be applied in electrocatalytic experiments for the promotion of different heterogeneously catalyzed reactions. The strong increase in catalytic activity of Pt/YSZ assemblies on electrochemical polarization has recently been attributed to the creation of catalytically active spill-over species under non-equilibrium conditions. Our experiments combine locally resolved surface sensitive techniques (SPEM, PEEM) with electrochemical methods in order to resolve the processes at the Pt/YSZ interface and to clarify the nature of the spillover species.
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: SOLID STATE IONICS, Vol. 136-137, 02.11.2000, p. 699-705.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Spatially resolved measurements of electrochemically induced spillover on porous and microstructured Pt/YSZ catalysts
AU - Imbihl, R.
AU - Janek, J.
N1 - Funding Information: The authors are indebted to C.G. Vayenas, Patras, for the supply of several Pt/YSZ samples used in their experiments. Financial support from the DFG (Deutsche Forschungsgemeinschaft) is gratefully acknowledged.
PY - 2000/11/2
Y1 - 2000/11/2
N2 - Pt/YSZ electrodes prepared from platinum (Pt) and yttria-stabilized zirconia (YSZ) can be applied in electrocatalytic experiments for the promotion of different heterogeneously catalyzed reactions. The strong increase in catalytic activity of Pt/YSZ assemblies on electrochemical polarization has recently been attributed to the creation of catalytically active spill-over species under non-equilibrium conditions. Our experiments combine locally resolved surface sensitive techniques (SPEM, PEEM) with electrochemical methods in order to resolve the processes at the Pt/YSZ interface and to clarify the nature of the spillover species.
AB - Pt/YSZ electrodes prepared from platinum (Pt) and yttria-stabilized zirconia (YSZ) can be applied in electrocatalytic experiments for the promotion of different heterogeneously catalyzed reactions. The strong increase in catalytic activity of Pt/YSZ assemblies on electrochemical polarization has recently been attributed to the creation of catalytically active spill-over species under non-equilibrium conditions. Our experiments combine locally resolved surface sensitive techniques (SPEM, PEEM) with electrochemical methods in order to resolve the processes at the Pt/YSZ interface and to clarify the nature of the spillover species.
UR - http://www.scopus.com/inward/record.url?scp=0034316648&partnerID=8YFLogxK
U2 - 10.1016/S0167-2738(00)00565-8
DO - 10.1016/S0167-2738(00)00565-8
M3 - Article
AN - SCOPUS:0034316648
VL - 136-137
SP - 699
EP - 705
JO - SOLID STATE IONICS
JF - SOLID STATE IONICS
SN - 0167-2738
ER -