Details
| Original language | English |
|---|---|
| Pages (from-to) | 12334-12338 |
| Number of pages | 5 |
| Journal | RSC Advances |
| Volume | 10 |
| Issue number | 21 |
| Publication status | Published - 26 Mar 2020 |
Abstract
A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H2abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different gases, but show a high selectivity against H2S, which makes this material promising for potential sensor applications.
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Chemical Engineering(all)
- General Chemical Engineering
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In: RSC Advances, Vol. 10, No. 21, 26.03.2020, p. 12334-12338.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Solvent-assisted linker exchange as a tool for the design of mixed-linker MIL-140D structured MOFs for highly selective detection of gaseous H2S
AU - Schulz, Marcel
AU - Marquardt, Nele
AU - Schäfer, Malte
AU - Heinemeyer, Thea
AU - Schaate, Andreas
N1 - Publisher Copyright: © 2020 The Royal Society of Chemistry.
PY - 2020/3/26
Y1 - 2020/3/26
N2 - A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H2abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different gases, but show a high selectivity against H2S, which makes this material promising for potential sensor applications.
AB - A MIL-140D-sdc framework has been used as a highly stable backbone for the introduction of 4,4′-azobenzene dicarboxylic acid (H2abdc) via solvent-assisted ligand exchange (SALE). The implemented azo groups can serve as coordination sites for copper ions. These can exchange ligands with different gases, but show a high selectivity against H2S, which makes this material promising for potential sensor applications.
UR - http://www.scopus.com/inward/record.url?scp=85083154685&partnerID=8YFLogxK
U2 - 10.1039/d0ra01164a
DO - 10.1039/d0ra01164a
M3 - Article
AN - SCOPUS:85083154685
VL - 10
SP - 12334
EP - 12338
JO - RSC Advances
JF - RSC Advances
SN - 2046-2069
IS - 21
ER -