TY - JOUR

T1 - Solubility of H2O and CO2 in shoshonitic melts at 1250°C and pressures from 50 to 400MPa

T2 - Implications for Campi Flegrei magmatic systems

AU - Vetere, Francesco

AU - Botcharnikov, Roman E.

AU - Holtz, Francois

AU - Behrens, Harald

AU - De Rosa, Rosanna

N1 - Funding Information: This research has been supported by Regione Calabria—Dipartimento 11 Cultura, Istruzione, Università, Ricerca, Innovazione tecnologica, Alta formazione on the frame "Tirocini di Ricerca" Misura 3.7 Azione A del POR Calabria 2000–2006 (Vetere-A2UNICAL049). Funding by the German Science foundation is acknowledged (DFG, grant BE1720/25). The authors acknowledge Otto Diedrich for the excellent work on the preparation of samples for analysis. We would like to thank Prof. Moore and a second anonymous reviewer for helpful comments improving the quality of the paper. This paper benefited of many discussions with PD. Dr. Guido Ventura (INGV Roma) concerning the Vulcanello and Campi Flegrei volcanic systems that greatly improved the quality of this manuscript. Copyright: Copyright 2011 Elsevier B.V., All rights reserved.

PY - 2011/5/30

Y1 - 2011/5/30

N2 - The solubility of H2O-CO2-bearing fluids in shoshonitic melts relevant to magmas of the Vulcanello peninsula and to mafic melts from magmas erupted at Campi Flegrei (Italy) was experimentally determined at pressures from 50 to 400MPa and at temperature of 1250°C. No quench crystals and less than 1vol.% bubles were observed in the rapid quenched glasses. H2O and CO2 contents in the experimental glasses were determined via Karl-Fischer Titration (KFT) and FTIR spectroscopy. For the quantification of volatile concentrations by IR spectroscopy we have calibrated the absorption coefficients of water-related and carbon-related IR bands for the shoshonitic composition. The determined absorption coefficients are 0.80±0.06L mol-1 cm-1 for the band at ~4500cm-1 (OH groups) and 1.02±0.03L mol-1 cm-1 for the band at ~5200cm-1 (H2O molecules). CO2 is bound in the shoshonitic glass as CO32- exclusively; its concentration was quantified by the peak height of the low wavenumber band of the doublet near 1430cm-1 using the calibrated absorption coefficient of 356±18L mol-1 cm-1.The H2O solubility in the shoshonitic melts is in the same range as observed for other natural aluminosilicate melts, i.e. 5.12±0.07wt.% at 200MPa and 7.92±0.07wt.% H2O at 400MPa. A non-linear variation of the H2O and CO2 solubility in the melts with increasing mole fraction of H2O (and thus decreasing mole fraction of CO2) in the fluid was observed at each investigated pressure. At 1250°C, the concentration of dissolved carbonate (expressed as CO2 component) in melts coexisting with nearly pure CO2 fluid increases from 307 to 2932ppm (±10% relative) as the pressure increases from 50 to 400MPa. The comparison of the dataset with available models predicting the H2O and CO2 concentrations in silicate melts coexisting with H2O-CO2-bearing fluids shows that the effect of melt composition is not calibrated appropriately in the models.The experimental data are used to re-evaluate the typical pressures of glass inclusions entrapment in phenocrysts from Minopoli2 eruption and the results indicate that the main magma chamber may have been located at a depth of ~ 4000 m.

AB - The solubility of H2O-CO2-bearing fluids in shoshonitic melts relevant to magmas of the Vulcanello peninsula and to mafic melts from magmas erupted at Campi Flegrei (Italy) was experimentally determined at pressures from 50 to 400MPa and at temperature of 1250°C. No quench crystals and less than 1vol.% bubles were observed in the rapid quenched glasses. H2O and CO2 contents in the experimental glasses were determined via Karl-Fischer Titration (KFT) and FTIR spectroscopy. For the quantification of volatile concentrations by IR spectroscopy we have calibrated the absorption coefficients of water-related and carbon-related IR bands for the shoshonitic composition. The determined absorption coefficients are 0.80±0.06L mol-1 cm-1 for the band at ~4500cm-1 (OH groups) and 1.02±0.03L mol-1 cm-1 for the band at ~5200cm-1 (H2O molecules). CO2 is bound in the shoshonitic glass as CO32- exclusively; its concentration was quantified by the peak height of the low wavenumber band of the doublet near 1430cm-1 using the calibrated absorption coefficient of 356±18L mol-1 cm-1.The H2O solubility in the shoshonitic melts is in the same range as observed for other natural aluminosilicate melts, i.e. 5.12±0.07wt.% at 200MPa and 7.92±0.07wt.% H2O at 400MPa. A non-linear variation of the H2O and CO2 solubility in the melts with increasing mole fraction of H2O (and thus decreasing mole fraction of CO2) in the fluid was observed at each investigated pressure. At 1250°C, the concentration of dissolved carbonate (expressed as CO2 component) in melts coexisting with nearly pure CO2 fluid increases from 307 to 2932ppm (±10% relative) as the pressure increases from 50 to 400MPa. The comparison of the dataset with available models predicting the H2O and CO2 concentrations in silicate melts coexisting with H2O-CO2-bearing fluids shows that the effect of melt composition is not calibrated appropriately in the models.The experimental data are used to re-evaluate the typical pressures of glass inclusions entrapment in phenocrysts from Minopoli2 eruption and the results indicate that the main magma chamber may have been located at a depth of ~ 4000 m.

KW - Campi Flegrei

KW - CO

KW - HO

KW - Shoshonitic magmas

KW - Solubility

KW - Vulcanello

UR - http://www.scopus.com/inward/record.url?scp=79955038579&partnerID=8YFLogxK

U2 - 10.1016/j.jvolgeores.2011.03.002

DO - 10.1016/j.jvolgeores.2011.03.002

M3 - Article

AN - SCOPUS:79955038579

VL - 202

SP - 251

EP - 261

JO - Journal of Volcanology and Geothermal Research

JF - Journal of Volcanology and Geothermal Research

SN - 0377-0273

IS - 3-4

ER -