Details
| Original language | English |
|---|---|
| Pages (from-to) | 1-102 |
| Number of pages | 102 |
| Journal | Annual Reports on NMR Spectroscopy |
| Volume | 89 |
| Early online date | 13 Jul 2016 |
| Publication status | Published - 2016 |
Abstract
Solid-state nuclear magnetic resonance (NMR) spectroscopy is an excellent characterization technique to investigate the local structure and dynamics of materials. This can be exploited to elucidate properties of lithium-containing materials which are systems with very interesting ion dynamics behavior. This review presents a collection of Li solid-state NMR studies on Li dynamics in Li-containing solids reported in the scientific literature. Lithium ion conductors which find use in lithium ion batteries have been given special attention with explanations of their ion dynamic mechanisms, activation barriers, jump rates and dimensionalities of diffusion pathways. The review mainly deals with ion diffusion properties of different classes of solid materials based on their structural and chemical identities. The wide variety of materials discussed include inorganic and organic crystalline and amorphous systems. A short introduction to the NMR methods to determine the diffusion parameters is also provided along with an introduction to the basics in diffusion in solids.
Keywords
- Activation energies, Beta-NMR, Diffusion in solids, Diffusion pathways, Exchange spectroscopy, Field gradient NMR, Ion jump rates, Lithium, Lithium ion dynamics, Nuclear spin relaxation, Solid-state NMR, Spin alignment echo NMR
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Chemistry(all)
- Spectroscopy
Sustainable Development Goals
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In: Annual Reports on NMR Spectroscopy, Vol. 89, 2016, p. 1-102.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Solid-State NMR Studies of Lithium Ion Dynamics Across Materials Classes
AU - Vinod Chandran, C.
AU - Heitjans, P.
N1 - Funding Information: The authors would like to acknowledge financial supports from Niedersächsisches Ministerium für Wissenschaft und Kultur (MWK) within the research program Graduiertenkolleg Energiespeicher und Elektromobilität Niedersachsen (GEENI) and from Deutsche Forschungsgemeinschaft (DFG) in the framework of the Research Unit FOR 1277 Mobilität von Ionen in Festkörpern (molife).
PY - 2016
Y1 - 2016
N2 - Solid-state nuclear magnetic resonance (NMR) spectroscopy is an excellent characterization technique to investigate the local structure and dynamics of materials. This can be exploited to elucidate properties of lithium-containing materials which are systems with very interesting ion dynamics behavior. This review presents a collection of Li solid-state NMR studies on Li dynamics in Li-containing solids reported in the scientific literature. Lithium ion conductors which find use in lithium ion batteries have been given special attention with explanations of their ion dynamic mechanisms, activation barriers, jump rates and dimensionalities of diffusion pathways. The review mainly deals with ion diffusion properties of different classes of solid materials based on their structural and chemical identities. The wide variety of materials discussed include inorganic and organic crystalline and amorphous systems. A short introduction to the NMR methods to determine the diffusion parameters is also provided along with an introduction to the basics in diffusion in solids.
AB - Solid-state nuclear magnetic resonance (NMR) spectroscopy is an excellent characterization technique to investigate the local structure and dynamics of materials. This can be exploited to elucidate properties of lithium-containing materials which are systems with very interesting ion dynamics behavior. This review presents a collection of Li solid-state NMR studies on Li dynamics in Li-containing solids reported in the scientific literature. Lithium ion conductors which find use in lithium ion batteries have been given special attention with explanations of their ion dynamic mechanisms, activation barriers, jump rates and dimensionalities of diffusion pathways. The review mainly deals with ion diffusion properties of different classes of solid materials based on their structural and chemical identities. The wide variety of materials discussed include inorganic and organic crystalline and amorphous systems. A short introduction to the NMR methods to determine the diffusion parameters is also provided along with an introduction to the basics in diffusion in solids.
KW - Activation energies
KW - Beta-NMR
KW - Diffusion in solids
KW - Diffusion pathways
KW - Exchange spectroscopy
KW - Field gradient NMR
KW - Ion jump rates
KW - Lithium
KW - Lithium ion dynamics
KW - Nuclear spin relaxation
KW - Solid-state NMR
KW - Spin alignment echo NMR
UR - http://www.scopus.com/inward/record.url?scp=84996802164&partnerID=8YFLogxK
U2 - 10.1016/bs.arnmr.2016.03.001
DO - 10.1016/bs.arnmr.2016.03.001
M3 - Article
AN - SCOPUS:84996802164
VL - 89
SP - 1
EP - 102
JO - Annual Reports on NMR Spectroscopy
JF - Annual Reports on NMR Spectroscopy
SN - 0066-4103
ER -