Details
| Original language | English |
|---|---|
| Pages (from-to) | 13868-13871 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 55 |
| Issue number | 92 |
| Publication status | Published - 31 Oct 2019 |
Abstract
A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52-0.79 s.
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Materials Science(all)
- Electronic, Optical and Magnetic Materials
- Materials Science(all)
- Ceramics and Composites
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- Surfaces, Coatings and Films
- Materials Science(all)
- Metals and Alloys
- Materials Science(all)
- Materials Chemistry
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In: Chemical Communications, Vol. 55, No. 92, 31.10.2019, p. 13868-13871.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex
AU - Rajnák, Cyril
AU - Titiš, Ján
AU - Moncoľ, Ján
AU - Renz, Franz
AU - Boča, Roman
N1 - Funding information: Slovak grant agencies (APVV 16-0039, APVV 18-0016, VEGA 1/ 0919/17 and VEGA 1/0013/18) along with the DAAD(D/SK) project are acknowledged for the financial support. Also, the projects NFP313010V954 of call OPVaI-VA/DP/2018/1.1.3-07 and ITMS 26240220084 cofounded by the European Regional Development Fund are acknowledged.
PY - 2019/10/31
Y1 - 2019/10/31
N2 - A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52-0.79 s.
AB - A mononuclear pentacoordinate iron(iii) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52-0.79 s.
UR - http://www.scopus.com/inward/record.url?scp=85074962559&partnerID=8YFLogxK
U2 - 10.1039/c9cc06610a
DO - 10.1039/c9cc06610a
M3 - Article
C2 - 31674626
AN - SCOPUS:85074962559
VL - 55
SP - 13868
EP - 13871
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 92
ER -