(S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene

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Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number3
Publication statusPublished - 18 Mar 2009

Abstract

The title compound, C16H18O2P2, possesses two stereogenic P atoms and shows a distorted s-cis conformation of each O=P - C=C moiety. This has been suggested on the basis of the stereochemical result of 1,3-dipolar cyclo-additions with nitro-nes and is now confirmed by the present crystal structure analysis. There are two crystallographically independent molecules in the asymmetric unit.

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(S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene. / Butenschön, Holger; Vinokurov, Nikolai; Baumgardt, Ingmar et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 65, No. 3, 18.03.2009.

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Butenschön, H, Vinokurov, N, Baumgardt, I & Pietrusiewicz, KM 2009, '(S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene', Acta Crystallographica Section E: Structure Reports Online, vol. 65, no. 3. https://doi.org/10.1107/S1600536809004632
Butenschön, H., Vinokurov, N., Baumgardt, I., & Pietrusiewicz, K. M. (2009). (S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene. Acta Crystallographica Section E: Structure Reports Online, 65(3). https://doi.org/10.1107/S1600536809004632
Butenschön H, Vinokurov N, Baumgardt I, Pietrusiewicz KM. (S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene. Acta Crystallographica Section E: Structure Reports Online. 2009 Mar 18;65(3). doi: 10.1107/S1600536809004632
Butenschön, Holger ; Vinokurov, Nikolai ; Baumgardt, Ingmar et al. / (S μp,S μp)-(-)-(E)-1,2-Bis(methyl-phenyl-phosphino-yl)ethene. In: Acta Crystallographica Section E: Structure Reports Online. 2009 ; Vol. 65, No. 3.
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abstract = "The title compound, C16H18O2P2, possesses two stereogenic P atoms and shows a distorted s-cis conformation of each O=P - C=C moiety. This has been suggested on the basis of the stereochemical result of 1,3-dipolar cyclo-additions with nitro-nes and is now confirmed by the present crystal structure analysis. There are two crystallographically independent molecules in the asymmetric unit.",
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AU - Vinokurov, Nikolai

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AU - Pietrusiewicz, K. Michal

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