Details
| Original language | English |
|---|---|
| Pages (from-to) | 4281-4284 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 29 |
| Issue number | 34 |
| Publication status | Published - 1988 |
| Externally published | Yes |
Abstract
Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Pharmacology, Toxicology and Pharmaceutics(all)
- Drug Discovery
- Chemistry(all)
- Organic Chemistry
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In: Tetrahedron Letters, Vol. 29, No. 34, 1988, p. 4281-4284.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Ring-opening of oxiranes by silyl-substituted allyl anions. A regiochemical chameleon
AU - Schaumann, Ernst
AU - Kirschning, Andreas
PY - 1988
Y1 - 1988
N2 - Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
AB - Lithiated allylsilanes 1 undergo smooth addition to epoxides 4 with variable α, γ regioselectivity yielding the C-silylated enols 5,7 and 6,8, respectively. γ-Selectivity can be successfully enhanced by use of cuprates.
UR - http://www.scopus.com/inward/record.url?scp=0000991923&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(00)80474-8
DO - 10.1016/S0040-4039(00)80474-8
M3 - Article
AN - SCOPUS:0000991923
VL - 29
SP - 4281
EP - 4284
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 34
ER -