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| Translated title of the contribution | Vierringöffnung eines Bicyclo[3.2.0]hepta-1,3-dienylcobalt(I)-Komplexes mit nachfolgender Cycloaddition |
|---|---|
| Original language | English |
| Pages (from-to) | 1057-1059 |
| Number of pages | 3 |
| Journal | Angewandte Chemie International Edition in English |
| Volume | 29 |
| Issue number | 9 |
| Publication status | Published - Sept 1990 |
| Externally published | Yes |
| Event | Chemiedozenten-Tagung - Ulm, Germany Duration: 1 Jan 1990 → … |
Abstract
The four‐membered ring of the cobalt complex 1 is opened at only 200°C. The resulting allyl diene system 2 can be trapped by [2 + 4] cycloaddition with dienophiles to give cycloadducts such as 3 in good yields. The stereochemistry of the cycloadducts is strongly influenced by the coordination behavior of the dienophile. L = tetraphenylcyclobutadiene, E = COOCH3. (Figure Presented.)
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
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In: Angewandte Chemie International Edition in English, Vol. 29, No. 9, 09.1990, p. 1057-1059.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Ring‐Opening of a Bicyclo[3.2.0]hepta‐1,3‐dienyl‐cobalt(I) Complex Followed by Cycloaddition
AU - Butenschön, Holger
PY - 1990/9
Y1 - 1990/9
N2 - The four‐membered ring of the cobalt complex 1 is opened at only 200°C. The resulting allyl diene system 2 can be trapped by [2 + 4] cycloaddition with dienophiles to give cycloadducts such as 3 in good yields. The stereochemistry of the cycloadducts is strongly influenced by the coordination behavior of the dienophile. L = tetraphenylcyclobutadiene, E = COOCH3. (Figure Presented.)
AB - The four‐membered ring of the cobalt complex 1 is opened at only 200°C. The resulting allyl diene system 2 can be trapped by [2 + 4] cycloaddition with dienophiles to give cycloadducts such as 3 in good yields. The stereochemistry of the cycloadducts is strongly influenced by the coordination behavior of the dienophile. L = tetraphenylcyclobutadiene, E = COOCH3. (Figure Presented.)
UR - http://www.scopus.com/inward/record.url?scp=33748245865&partnerID=8YFLogxK
U2 - 10.1002/anie.199010571
DO - 10.1002/anie.199010571
M3 - Article
AN - SCOPUS:33748245865
VL - 29
SP - 1057
EP - 1059
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
SN - 0570-0833
IS - 9
T2 - Chemiedozenten-Tagung
Y2 - 1 January 1990
ER -