Details
| Original language | English |
|---|---|
| Article number | 52215 |
| Journal | Journal of applied polymer science |
| Volume | 139 |
| Issue number | 21 |
| Publication status | Published - 1 Apr 2022 |
Abstract
An efficient use of plasticizers in rubber compounds requires an understanding of their miscibility behavior. Besides the chemical properties of both rubber and plasticizer, the rigidity of the plasticizer plays an important role for their miscibility. The miscibility is investigated here using the glass transition measured by differential scanning calorimetry and broadband dielectric spectroscopy (BDS). Additionally, the interfacial relaxation and phase separation measured by BDS are confirmed by transmission electron microscopy. While the flexible plasticizer, poly-(α-methylstyrene), stays miscible in a silica-filled polybutadiene rubber compound, the more rigid plasticizer, indene-coumarone (IC), shows a phase separation at high concentrations. The phase-separated IC tends to accumulate at the silica surface.
Keywords
- dielectric properties, glass Transition, plasticizer, resins, rubber
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- Surfaces, Coatings and Films
- Materials Science(all)
- Polymers and Plastics
- Materials Science(all)
- Materials Chemistry
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In: Journal of applied polymer science, Vol. 139, No. 21, 52215, 01.04.2022.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Rigidity of plasticizers and their miscibility in silica-filled polybutadiene rubber by broadband dielectric spectroscopy
AU - Lindemann, Niclas
AU - Finger, Sebastian
AU - Karimi-Varzaneh, Hossein Ali
AU - Lacayo-Pineda, Jorge
N1 - Funding Information: This research was funded by the European Union's Horizon 2020 research and innovation program project VIMMP, grant agreement number 760907.
PY - 2022/4/1
Y1 - 2022/4/1
N2 - An efficient use of plasticizers in rubber compounds requires an understanding of their miscibility behavior. Besides the chemical properties of both rubber and plasticizer, the rigidity of the plasticizer plays an important role for their miscibility. The miscibility is investigated here using the glass transition measured by differential scanning calorimetry and broadband dielectric spectroscopy (BDS). Additionally, the interfacial relaxation and phase separation measured by BDS are confirmed by transmission electron microscopy. While the flexible plasticizer, poly-(α-methylstyrene), stays miscible in a silica-filled polybutadiene rubber compound, the more rigid plasticizer, indene-coumarone (IC), shows a phase separation at high concentrations. The phase-separated IC tends to accumulate at the silica surface.
AB - An efficient use of plasticizers in rubber compounds requires an understanding of their miscibility behavior. Besides the chemical properties of both rubber and plasticizer, the rigidity of the plasticizer plays an important role for their miscibility. The miscibility is investigated here using the glass transition measured by differential scanning calorimetry and broadband dielectric spectroscopy (BDS). Additionally, the interfacial relaxation and phase separation measured by BDS are confirmed by transmission electron microscopy. While the flexible plasticizer, poly-(α-methylstyrene), stays miscible in a silica-filled polybutadiene rubber compound, the more rigid plasticizer, indene-coumarone (IC), shows a phase separation at high concentrations. The phase-separated IC tends to accumulate at the silica surface.
KW - dielectric properties
KW - glass Transition
KW - plasticizer
KW - resins
KW - rubber
UR - http://www.scopus.com/inward/record.url?scp=85124544928&partnerID=8YFLogxK
U2 - 10.1002/app.52215
DO - 10.1002/app.52215
M3 - Article
AN - SCOPUS:85124544928
VL - 139
JO - Journal of applied polymer science
JF - Journal of applied polymer science
SN - 0021-8995
IS - 21
M1 - 52215
ER -