Reference Electrodes in Proton Exchange Membrane Water Electrolysis: Previous Approaches, Current Application, and Perspectives

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Original languageEnglish
Article number054519
Number of pages12
JournalJournal of the Electrochemical Society
Volume171
Issue number5
Publication statusPublished - 29 May 2024

Abstract

The commercialization of proton exchange membrane water electrolysis cells (PEMWEs), which are essential for a greener and more sustainable future, is hindered by the high costs of noble metal catalysts, as well as the degradation of the catalysts and membranes. Examining the electrodes’ characteristics with reference electrodes (REs) yields insights into their individual performance and can, e.g., help assess new catalyst layer designs, their interplay with the adjacent porous transport layer, or understand the complex and multi-faceted degradation mechanisms. This review provides an overview of previous approaches and the evolution of RE designs in PEMWE. By discussing the strengths and limitations of different RE setups, readers are enabled to make more informed decisions about their experiments’ design and choose the best RE setup for their specific research question.

Keywords

    degradation, half-cell characterization, proton exchange membrane water electrolysis, reference electrodes, research methodology

ASJC Scopus subject areas

Sustainable Development Goals

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Reference Electrodes in Proton Exchange Membrane Water Electrolysis: Previous Approaches, Current Application, and Perspectives. / Bühre, Lena V.; Bensmann, Boris; Hanke-Rauschenbach, Richard.
In: Journal of the Electrochemical Society, Vol. 171, No. 5, 054519, 29.05.2024.

Research output: Contribution to journalReview articleResearchpeer review

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AU - Bensmann, Boris

AU - Hanke-Rauschenbach, Richard

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