Details
| Original language | English |
|---|---|
| Pages (from-to) | 2101-2104 |
| Number of pages | 4 |
| Journal | Organic Letters |
| Volume | 1 |
| Issue number | 13 |
| Publication status | Published - 30 Nov 1999 |
| Externally published | Yes |
Abstract
(matrix presented) Preparation of new polymer-supported electrophilic reagents that efficiently promote 1,2-haloacetoxylations of alkenes and alkoxyallenes is described. Under very mild conditions and in high yields, alkenes are transformed into α-halo acetates while alkoxyallenes lead to vinyl iodides. In contrast to these results, terminal alkynes commonly afford synthetically valuable 1-iodo-alkynes. † Technischen Universität Clausthal. ‡ Willamette University.
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biochemistry
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
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In: Organic Letters, Vol. 1, No. 13, 30.11.1999, p. 2101-2104.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Reactions of alkenes, alkynes, and alkoxyallenes with new polymer-supported electrophilic reagents
AU - Monenschein, Holger
AU - Sourkouni-Argirusi, Georgia
AU - Schubothe, Katherine M.
AU - O'Hare, Thomas
AU - Kirschning, Andreas
PY - 1999/11/30
Y1 - 1999/11/30
N2 - (matrix presented) Preparation of new polymer-supported electrophilic reagents that efficiently promote 1,2-haloacetoxylations of alkenes and alkoxyallenes is described. Under very mild conditions and in high yields, alkenes are transformed into α-halo acetates while alkoxyallenes lead to vinyl iodides. In contrast to these results, terminal alkynes commonly afford synthetically valuable 1-iodo-alkynes. † Technischen Universität Clausthal. ‡ Willamette University.
AB - (matrix presented) Preparation of new polymer-supported electrophilic reagents that efficiently promote 1,2-haloacetoxylations of alkenes and alkoxyallenes is described. Under very mild conditions and in high yields, alkenes are transformed into α-halo acetates while alkoxyallenes lead to vinyl iodides. In contrast to these results, terminal alkynes commonly afford synthetically valuable 1-iodo-alkynes. † Technischen Universität Clausthal. ‡ Willamette University.
UR - http://www.scopus.com/inward/record.url?scp=0000940686&partnerID=8YFLogxK
U2 - 10.1021/ol991149m
DO - 10.1021/ol991149m
M3 - Article
AN - SCOPUS:0000940686
VL - 1
SP - 2101
EP - 2104
JO - Organic Letters
JF - Organic Letters
SN - 1523-7060
IS - 13
ER -