Details
| Original language | English |
|---|---|
| Pages (from-to) | 893-896 |
| Number of pages | 4 |
| Journal | ORGANOMETALLICS |
| Volume | 17 |
| Issue number | 5 |
| Publication status | Published - 6 Feb 1998 |
Abstract
(Di-tert-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
- Chemistry(all)
- Inorganic Chemistry
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In: ORGANOMETALLICS, Vol. 17, No. 5, 06.02.1998, p. 893-896.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Reactions of a Chelated Cyclopentadienylcobalt(I) Complex with 3,3-Disubstituted Cyclopropenes
T2 - Formation of Isoprene, Vinylcarbene, and 1-Phosphadiene Ligands at the Metal
AU - Foerstner, Jan
AU - Kakoschke, Alf
AU - Stellfeldt, Dirk
AU - Butenschön, Holger
AU - Wartchow, Rudolf
PY - 1998/2/6
Y1 - 1998/2/6
N2 - (Di-tert-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.
AB - (Di-tert-butylphosphanyl-P-ethyl)cyclopentadienylcobalt(I) complexes 1 and 2 were treated with 3,3-disubstituted cyclopropenes to give isoprene and vinylcarbene complexes. The diphenylvinylcarbene complex reacted with tert-butylphosphaethyne to give unusual coupling products.
UR - http://www.scopus.com/inward/record.url?scp=0000569615&partnerID=8YFLogxK
U2 - 10.1021/om970851o
DO - 10.1021/om970851o
M3 - Article
AN - SCOPUS:0000569615
VL - 17
SP - 893
EP - 896
JO - ORGANOMETALLICS
JF - ORGANOMETALLICS
SN - 0276-7333
IS - 5
ER -