Details
| Original language | English |
|---|---|
| Pages (from-to) | 1410-1412 |
| Number of pages | 3 |
| Journal | Chemistry of Materials |
| Volume | 21 |
| Issue number | 8 |
| Early online date | 26 Mar 2009 |
| Publication status | Published - 28 Apr 2009 |
Abstract
The rapid room-temperature synthesis and characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework (ZIF) material has been reported. Comparison of an X-ray diffraction (XRD) pattern taken from a powder sample with a pattern simulated from structure demonstrates that the product is single-phase ZIF-8 material. The mixing, microwave, ultrasound, and microemulsion methods have been used for synthesis and achieving some degree of size and shape. Such preformed nanocrystals should be excellent candidates for the preparation of supported ZIF films and membranes, as known for zeolites. nanoscale microporous adsorbents and catalysts are favorable over microscale ones with regard to the mass and energy transport properties. method of excess protic linker might be a general one and transferable to other ZIFs, and even carboxylate-based MOFs at low pH conditions.
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
- Materials Science(all)
- Materials Chemistry
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In: Chemistry of Materials, Vol. 21, No. 8, 28.04.2009, p. 1410-1412.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Rapid room-temperature synthesis and characterization of nanocrystals of a prototypical zeolitic imidazolate framework
AU - Cravillon, Janosch
AU - Münzer, Simon
AU - Lohmeier, Sven Jare
AU - Feldhoff, Armin
AU - Huber, Klaus
AU - Wiebcke, Michael
PY - 2009/4/28
Y1 - 2009/4/28
N2 - The rapid room-temperature synthesis and characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework (ZIF) material has been reported. Comparison of an X-ray diffraction (XRD) pattern taken from a powder sample with a pattern simulated from structure demonstrates that the product is single-phase ZIF-8 material. The mixing, microwave, ultrasound, and microemulsion methods have been used for synthesis and achieving some degree of size and shape. Such preformed nanocrystals should be excellent candidates for the preparation of supported ZIF films and membranes, as known for zeolites. nanoscale microporous adsorbents and catalysts are favorable over microscale ones with regard to the mass and energy transport properties. method of excess protic linker might be a general one and transferable to other ZIFs, and even carboxylate-based MOFs at low pH conditions.
AB - The rapid room-temperature synthesis and characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework (ZIF) material has been reported. Comparison of an X-ray diffraction (XRD) pattern taken from a powder sample with a pattern simulated from structure demonstrates that the product is single-phase ZIF-8 material. The mixing, microwave, ultrasound, and microemulsion methods have been used for synthesis and achieving some degree of size and shape. Such preformed nanocrystals should be excellent candidates for the preparation of supported ZIF films and membranes, as known for zeolites. nanoscale microporous adsorbents and catalysts are favorable over microscale ones with regard to the mass and energy transport properties. method of excess protic linker might be a general one and transferable to other ZIFs, and even carboxylate-based MOFs at low pH conditions.
UR - http://www.scopus.com/inward/record.url?scp=66149125688&partnerID=8YFLogxK
U2 - 10.1021/cm900166h
DO - 10.1021/cm900166h
M3 - Article
AN - SCOPUS:66149125688
VL - 21
SP - 1410
EP - 1412
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 8
ER -