Details
| Original language | English |
|---|---|
| Pages (from-to) | 80-83 |
| Number of pages | 4 |
| Journal | Journal of molecular spectroscopy |
| Volume | 335 |
| Early online date | 2 Mar 2017 |
| Publication status | Published - May 2017 |
Abstract
The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
Keywords
- Boron trifluoride, Carbon monoxide, Pulsed jet, Rotational spectroscopy, van der Waals complex
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Physical and Theoretical Chemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: Journal of molecular spectroscopy, Vol. 335, 05.2017, p. 80-83.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Pulsed jet Fourier transform microwave spectroscopy of the BF3-CO complex
AU - Feng, Gang
AU - Gou, Qian
AU - Evangelisti, Luca
AU - Grabow, Jens Uwe
AU - Caminati, Walther
N1 - Funding Information: We thank the MIUR (PRIN project 2010ERFKXL_001) and the University of Bologna (RFO) for financial support. We acknowledge the CINECA award under the ISCRA initiative, for the availability of high performance computing resources and support. JUG thanks the DFG for financial support. Publisher Copyright: © 2017 Elsevier Inc. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2017/5
Y1 - 2017/5
N2 - The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
AB - The rotational spectrum of the van der Waals complex between BF3 and CO was studied using a pulse jet Fourier transform microwave spectrometer, which renewed the electric resonance spectroscopic measurements by Klemperer et al. [J. Am. Chem. Soc. 100 (1978) 8074]. The spectral measurements have been considerably extended and the newly assigned rotational spectrum of the isotopologue BF3-C18O allowed for a precise structural analysis confirming the effective collinearity of the atoms B, C and O in the complex.
KW - Boron trifluoride
KW - Carbon monoxide
KW - Pulsed jet
KW - Rotational spectroscopy
KW - van der Waals complex
UR - http://www.scopus.com/inward/record.url?scp=85018770121&partnerID=8YFLogxK
U2 - 10.1016/j.jms.2017.03.001
DO - 10.1016/j.jms.2017.03.001
M3 - Article
AN - SCOPUS:85018770121
VL - 335
SP - 80
EP - 83
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
SN - 0022-2852
ER -