Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements

Research output: Contribution to journalArticleResearchpeer review

Authors

  • H. K. Tchakouté
  • D. E. Tchinda Mabah
  • C. Henning Rüscher
  • E. Kamseu
  • F. Andreola
  • M. C. Bignozzi
  • C. Leonelli

Research Organisations

External Research Organisations

  • University of Yaounde I
  • University of Modena and Reggio Emilia
  • University of Bologna
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Details

Original languageEnglish
Pages (from-to)149-161
Number of pages13
JournalJournal of Asian Ceramic Societies
Volume8
Issue number1
Publication statusPublished - 28 Jan 2020

Abstract

This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

Keywords

    geopolymer cements, Metakaolin, microcomposite, nanocomposite, sodium waterglass

ASJC Scopus subject areas

Cite this

Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. / Tchakouté, H. K.; Tchinda Mabah, D. E.; Henning Rüscher, C. et al.
In: Journal of Asian Ceramic Societies, Vol. 8, No. 1, 28.01.2020, p. 149-161.

Research output: Contribution to journalArticleResearchpeer review

Tchakouté, HK, Tchinda Mabah, DE, Henning Rüscher, C, Kamseu, E, Andreola, F, Bignozzi, MC & Leonelli, C 2020, 'Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements', Journal of Asian Ceramic Societies, vol. 8, no. 1, pp. 149-161. https://doi.org/10.1080/21870764.2020.1718860, https://doi.org/10.15488/10710
Tchakouté, H. K., Tchinda Mabah, D. E., Henning Rüscher, C., Kamseu, E., Andreola, F., Bignozzi, M. C., & Leonelli, C. (2020). Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. Journal of Asian Ceramic Societies, 8(1), 149-161. https://doi.org/10.1080/21870764.2020.1718860, https://doi.org/10.15488/10710
Tchakouté HK, Tchinda Mabah DE, Henning Rüscher C, Kamseu E, Andreola F, Bignozzi MC et al. Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. Journal of Asian Ceramic Societies. 2020 Jan 28;8(1):149-161. doi: 10.1080/21870764.2020.1718860, 10.15488/10710
Tchakouté, H. K. ; Tchinda Mabah, D. E. ; Henning Rüscher, C. et al. / Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements. In: Journal of Asian Ceramic Societies. 2020 ; Vol. 8, No. 1. pp. 149-161.
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title = "Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements",
abstract = "This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.",
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note = "Funding Information: Dr. Herv{\'e} Tchakout{\'e} Kouamo gratefully acknowledges the Alexander von Humboldt Foundation for financial support this work under the grant N° KAM/1155741 GFHERMES-P. The authors would like to thank Dr. Valerie Petrov for SEM observations. ",
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TY - JOUR

T1 - Preparation of low-cost nano and microcomposites from chicken eggshell, nano-silica and rice husk ash and their utilisations as additives for producing geopolymer cements

AU - Tchakouté, H. K.

AU - Tchinda Mabah, D. E.

AU - Henning Rüscher, C.

AU - Kamseu, E.

AU - Andreola, F.

AU - Bignozzi, M. C.

AU - Leonelli, C.

N1 - Funding Information: Dr. Hervé Tchakouté Kouamo gratefully acknowledges the Alexander von Humboldt Foundation for financial support this work under the grant N° KAM/1155741 GFHERMES-P. The authors would like to thank Dr. Valerie Petrov for SEM observations.

PY - 2020/1/28

Y1 - 2020/1/28

N2 - This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

AB - This work aims to prepare low-cost nanocomposite and microcomposite with lower molar ratio CaO/SiO2 (0.4). Nano-silica, rice husk ash and calcined chicken eggshell have been used as silica and calcium sources. Metakaolin has been separately replaced by 0, 10 and 20 wt% of each composite in order to study their behavior on the properties of geopolymers. The hardener used is sodium waterglass from rice husk ash. The surface area of nano-silica and rice husk ash was 54.40 and 4.08 m2/g, respectively. The cumulative volumes of the control geopolymer, the ones containing 10 wt% of microcomposite and nanocomposite are 119.71, 89.92 and 110.49 mm3/g, respectively. The compressive strength of the control specimen is around 64.02 MPa. The one using 10 wt% of microcomposite was 68.97 MPa. It drops to 42.88 MPa when metakaolin was replaced by 20 wt % of microcomposite. Whereas the one using 10 wt% of nanocomposite was 30.03 MPa and it decreases to 26.05 MPa when metakaolin was substituted by 20 wt% of nanocomposite. It can be concluded that 10 wt% of microcomposite could be mixed to metakaolin for strength development and nanocomposite does not recommend to use as an additive for producing high strength of geopolymer cements.

KW - geopolymer cements

KW - Metakaolin

KW - microcomposite

KW - nanocomposite

KW - sodium waterglass

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DO - 10.1080/21870764.2020.1718860

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EP - 161

JO - Journal of Asian Ceramic Societies

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