Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Hendrik Spende
  • Christoph Margenfeld
  • Tobias Meyer
  • Irene Manglano Clavero
  • Heiko Bremers
  • Andreas Hangleiter
  • Michael Seibt
  • Andreas Waag
  • Andrey Bakin

External Research Organisations

  • Technische Universität Braunschweig
  • University of Göttingen
View graph of relations

Details

Original languageEnglish
Article number035006
JournalSemiconductor Science and Technology
Volume35
Issue number3
Publication statusPublished - 2020
Externally publishedYes

Abstract

Plasma profiling time of flight mass spectrometry (PP-TOFMS) has recently gained interest as it enables the elemental profiling of semiconductor structures with high depth resolution in short acquisition times. As recently shown by Tempez et al PP-TOFMS can be used to obtain the composition within structures of modern field effect transistors [1]. There, the results were compared to conventional SIMS measurements. In the present study, we compare PP-TOFMS measurements of an Al-/In-/GaN quantum well multi stack to established micro- and nanoanalysis techniques like cathodoluminescence (CL), scanning transmission electron microscopy (STEM), energy dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). We show that PP-TOFMS is able to resolve the layer structure of the sample even more than 500 nm deep into the sample and allows the determination of a relative elemental composition with an accuracy of about 10 rel%. Therefore, it is an extremely rapid alternative method to obtain semiconductor elemental depth profiles without the expensive and time consuming sample preparation required for TEM. Besides, PP-TOFMS offers better depth resolution and more elemental information than, for example, electrochemical capacitance-voltage (ECV) evaluations, since all elements are detected in parallel and not only electrically (ECV) or optically (CL) active elements are observed.

Keywords

    AlGaN, GaN, InGaN, MQW, PP-TOFMS, TEM, XRD

ASJC Scopus subject areas

Cite this

Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range. / Spende, Hendrik; Margenfeld, Christoph; Meyer, Tobias et al.
In: Semiconductor Science and Technology, Vol. 35, No. 3, 035006, 2020.

Research output: Contribution to journalArticleResearchpeer review

Spende, H., Margenfeld, C., Meyer, T., Clavero, I. M., Bremers, H., Hangleiter, A., Seibt, M., Waag, A., & Bakin, A. (2020). Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range. Semiconductor Science and Technology, 35(3), Article 035006. https://doi.org/10.1088/1361-6641/ab6ac0
Spende H, Margenfeld C, Meyer T, Clavero IM, Bremers H, Hangleiter A et al. Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range. Semiconductor Science and Technology. 2020;35(3):035006. doi: 10.1088/1361-6641/ab6ac0
Download
@article{52d822c8052a430fbb37b6ef3dc3c350,
title = "Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range",
abstract = "Plasma profiling time of flight mass spectrometry (PP-TOFMS) has recently gained interest as it enables the elemental profiling of semiconductor structures with high depth resolution in short acquisition times. As recently shown by Tempez et al PP-TOFMS can be used to obtain the composition within structures of modern field effect transistors [1]. There, the results were compared to conventional SIMS measurements. In the present study, we compare PP-TOFMS measurements of an Al-/In-/GaN quantum well multi stack to established micro- and nanoanalysis techniques like cathodoluminescence (CL), scanning transmission electron microscopy (STEM), energy dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). We show that PP-TOFMS is able to resolve the layer structure of the sample even more than 500 nm deep into the sample and allows the determination of a relative elemental composition with an accuracy of about 10 rel%. Therefore, it is an extremely rapid alternative method to obtain semiconductor elemental depth profiles without the expensive and time consuming sample preparation required for TEM. Besides, PP-TOFMS offers better depth resolution and more elemental information than, for example, electrochemical capacitance-voltage (ECV) evaluations, since all elements are detected in parallel and not only electrically (ECV) or optically (CL) active elements are observed.",
keywords = "AlGaN, GaN, InGaN, MQW, PP-TOFMS, TEM, XRD",
author = "Hendrik Spende and Christoph Margenfeld and Tobias Meyer and Clavero, {Irene Manglano} and Heiko Bremers and Andreas Hangleiter and Michael Seibt and Andreas Waag and Andrey Bakin",
note = "Publisher Copyright: {\textcopyright} 2020 The Author(s). Published by IOP Publishing Ltd.",
year = "2020",
doi = "10.1088/1361-6641/ab6ac0",
language = "English",
volume = "35",
journal = "Semiconductor Science and Technology",
issn = "0268-1242",
publisher = "IOP Publishing Ltd.",
number = "3",

}

Download

TY - JOUR

T1 - Plasma profiling time-of-flight mass spectrometry for fast elemental analysis of semiconductor structures with depth resolution in the nanometer range

AU - Spende, Hendrik

AU - Margenfeld, Christoph

AU - Meyer, Tobias

AU - Clavero, Irene Manglano

AU - Bremers, Heiko

AU - Hangleiter, Andreas

AU - Seibt, Michael

AU - Waag, Andreas

AU - Bakin, Andrey

N1 - Publisher Copyright: © 2020 The Author(s). Published by IOP Publishing Ltd.

PY - 2020

Y1 - 2020

N2 - Plasma profiling time of flight mass spectrometry (PP-TOFMS) has recently gained interest as it enables the elemental profiling of semiconductor structures with high depth resolution in short acquisition times. As recently shown by Tempez et al PP-TOFMS can be used to obtain the composition within structures of modern field effect transistors [1]. There, the results were compared to conventional SIMS measurements. In the present study, we compare PP-TOFMS measurements of an Al-/In-/GaN quantum well multi stack to established micro- and nanoanalysis techniques like cathodoluminescence (CL), scanning transmission electron microscopy (STEM), energy dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). We show that PP-TOFMS is able to resolve the layer structure of the sample even more than 500 nm deep into the sample and allows the determination of a relative elemental composition with an accuracy of about 10 rel%. Therefore, it is an extremely rapid alternative method to obtain semiconductor elemental depth profiles without the expensive and time consuming sample preparation required for TEM. Besides, PP-TOFMS offers better depth resolution and more elemental information than, for example, electrochemical capacitance-voltage (ECV) evaluations, since all elements are detected in parallel and not only electrically (ECV) or optically (CL) active elements are observed.

AB - Plasma profiling time of flight mass spectrometry (PP-TOFMS) has recently gained interest as it enables the elemental profiling of semiconductor structures with high depth resolution in short acquisition times. As recently shown by Tempez et al PP-TOFMS can be used to obtain the composition within structures of modern field effect transistors [1]. There, the results were compared to conventional SIMS measurements. In the present study, we compare PP-TOFMS measurements of an Al-/In-/GaN quantum well multi stack to established micro- and nanoanalysis techniques like cathodoluminescence (CL), scanning transmission electron microscopy (STEM), energy dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). We show that PP-TOFMS is able to resolve the layer structure of the sample even more than 500 nm deep into the sample and allows the determination of a relative elemental composition with an accuracy of about 10 rel%. Therefore, it is an extremely rapid alternative method to obtain semiconductor elemental depth profiles without the expensive and time consuming sample preparation required for TEM. Besides, PP-TOFMS offers better depth resolution and more elemental information than, for example, electrochemical capacitance-voltage (ECV) evaluations, since all elements are detected in parallel and not only electrically (ECV) or optically (CL) active elements are observed.

KW - AlGaN

KW - GaN

KW - InGaN

KW - MQW

KW - PP-TOFMS

KW - TEM

KW - XRD

UR - http://www.scopus.com/inward/record.url?scp=85082242292&partnerID=8YFLogxK

U2 - 10.1088/1361-6641/ab6ac0

DO - 10.1088/1361-6641/ab6ac0

M3 - Article

AN - SCOPUS:85082242292

VL - 35

JO - Semiconductor Science and Technology

JF - Semiconductor Science and Technology

SN - 0268-1242

IS - 3

M1 - 035006

ER -