Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing

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Original languageEnglish
Article number2200395
Number of pages9
JournalAdvanced Materials Technologies
Volume7
Issue number12
Publication statusPublished - Dec 2022

Abstract

An easily fabricated gas sensor based on planar polymer optical waveguides with an integrated zeolite imidazole framework-8 (ZIF-8) thin film is presented for carbon dioxide detection and sensing. The planar optical waveguides are made of polymethylmethacrylate and fabricated by hot embossing, which makes it flexible and cost-efficient. Thin ZIF-8 films are uniformly grown on the waveguides surface through a simple solution method, which is crucial for the envisioned production of metal organic framework-based sensing devices on a large scale. Experimental results show that the produced optical elements exhibit a sensitivity of ≈2.5 μW/5 vol% toward carbon dioxide (CO2) with very rapid response time (≈6 s) and excellent reversibility of adsorption and desorption of the gas molecules. The demonstrated planar polymer sensing devices provide the potential to develop flexible on-chip gas sensors in an inexpensive and reproducible way.

Keywords

    gas sensors, metal-organic frameworks, optical sensing, optical waveguides, planar polymer waveguides

ASJC Scopus subject areas

Cite this

Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing. / Zheng, Lei; Keppler, Nils; Zhang, Huajun et al.
In: Advanced Materials Technologies, Vol. 7, No. 12, 2200395, 12.2022.

Research output: Contribution to journalArticleResearchpeer review

Zheng, L, Keppler, N, Zhang, H, Behrens, P & Roth, B 2022, 'Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing', Advanced Materials Technologies, vol. 7, no. 12, 2200395. https://doi.org/10.1002/admt.202200395
Zheng, L., Keppler, N., Zhang, H., Behrens, P., & Roth, B. (2022). Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing. Advanced Materials Technologies, 7(12), Article 2200395. https://doi.org/10.1002/admt.202200395
Zheng L, Keppler N, Zhang H, Behrens P, Roth B. Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing. Advanced Materials Technologies. 2022 Dec;7(12):2200395. doi: 10.1002/admt.202200395
Zheng, Lei ; Keppler, Nils ; Zhang, Huajun et al. / Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing. In: Advanced Materials Technologies. 2022 ; Vol. 7, No. 12.
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title = "Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing",
abstract = "An easily fabricated gas sensor based on planar polymer optical waveguides with an integrated zeolite imidazole framework-8 (ZIF-8) thin film is presented for carbon dioxide detection and sensing. The planar optical waveguides are made of polymethylmethacrylate and fabricated by hot embossing, which makes it flexible and cost-efficient. Thin ZIF-8 films are uniformly grown on the waveguides surface through a simple solution method, which is crucial for the envisioned production of metal organic framework-based sensing devices on a large scale. Experimental results show that the produced optical elements exhibit a sensitivity of ≈2.5 μW/5 vol% toward carbon dioxide (CO2) with very rapid response time (≈6 s) and excellent reversibility of adsorption and desorption of the gas molecules. The demonstrated planar polymer sensing devices provide the potential to develop flexible on-chip gas sensors in an inexpensive and reproducible way.",
keywords = "gas sensors, metal-organic frameworks, optical sensing, optical waveguides, planar polymer waveguides",
author = "Lei Zheng and Nils Keppler and Huajun Zhang and Peter Behrens and Bernhard Roth",
note = "Funding Information: L.Z. and N.K. contributed equally to this work. The authors acknowledge the financial support from the German Research Foundation (DFG) under Germany's Excellence Strategy within the Cluster of Excellence PhoenixD (EXC 2122, Project ID 390833453).",
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TY - JOUR

T1 - Planar Polymer Optical Waveguide with Metal-Organic Framework Coating for Carbon Dioxide Sensing

AU - Zheng, Lei

AU - Keppler, Nils

AU - Zhang, Huajun

AU - Behrens, Peter

AU - Roth, Bernhard

N1 - Funding Information: L.Z. and N.K. contributed equally to this work. The authors acknowledge the financial support from the German Research Foundation (DFG) under Germany's Excellence Strategy within the Cluster of Excellence PhoenixD (EXC 2122, Project ID 390833453).

PY - 2022/12

Y1 - 2022/12

N2 - An easily fabricated gas sensor based on planar polymer optical waveguides with an integrated zeolite imidazole framework-8 (ZIF-8) thin film is presented for carbon dioxide detection and sensing. The planar optical waveguides are made of polymethylmethacrylate and fabricated by hot embossing, which makes it flexible and cost-efficient. Thin ZIF-8 films are uniformly grown on the waveguides surface through a simple solution method, which is crucial for the envisioned production of metal organic framework-based sensing devices on a large scale. Experimental results show that the produced optical elements exhibit a sensitivity of ≈2.5 μW/5 vol% toward carbon dioxide (CO2) with very rapid response time (≈6 s) and excellent reversibility of adsorption and desorption of the gas molecules. The demonstrated planar polymer sensing devices provide the potential to develop flexible on-chip gas sensors in an inexpensive and reproducible way.

AB - An easily fabricated gas sensor based on planar polymer optical waveguides with an integrated zeolite imidazole framework-8 (ZIF-8) thin film is presented for carbon dioxide detection and sensing. The planar optical waveguides are made of polymethylmethacrylate and fabricated by hot embossing, which makes it flexible and cost-efficient. Thin ZIF-8 films are uniformly grown on the waveguides surface through a simple solution method, which is crucial for the envisioned production of metal organic framework-based sensing devices on a large scale. Experimental results show that the produced optical elements exhibit a sensitivity of ≈2.5 μW/5 vol% toward carbon dioxide (CO2) with very rapid response time (≈6 s) and excellent reversibility of adsorption and desorption of the gas molecules. The demonstrated planar polymer sensing devices provide the potential to develop flexible on-chip gas sensors in an inexpensive and reproducible way.

KW - gas sensors

KW - metal-organic frameworks

KW - optical sensing

KW - optical waveguides

KW - planar polymer waveguides

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