Details
| Original language | English |
|---|---|
| Article number | e202200701 |
| Journal | European Journal of Organic Chemistry |
| Volume | 2022 |
| Issue number | 41 |
| Early online date | 9 Aug 2022 |
| Publication status | Published - 2 Nov 2022 |
Abstract
Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
Keywords
- 1,3-Acyl shift, Natural products, Photochemistry, Terpenes, Total synthesis
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Organic Chemistry
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In: European Journal of Organic Chemistry, Vol. 2022, No. 41, e202200701, 02.11.2022.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Photochemical 1,3-Acyl Shifts in Natural Product Synthesis
AU - Lübken, Dennis
AU - Siekmeyer, Björn
AU - Kalesse, Markus
N1 - Funding Information: Open Access funding enabled and organized by Projekt DEAL.
PY - 2022/11/2
Y1 - 2022/11/2
N2 - Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
AB - Photochemical, sigmatropic 1,3-acyl shifts represent a powerful tool to construct quaternary carbon atoms and the backbones of complex natural products which cannot be constructed easily by conventional methods. This review highlights applications of 1,3-acyl shifts to elegant, partly biomimetic total syntheses of natural products by discussing the underlying photochemical equilibrium.
KW - 1,3-Acyl shift
KW - Natural products
KW - Photochemistry
KW - Terpenes
KW - Total synthesis
UR - http://www.scopus.com/inward/record.url?scp=85138431393&partnerID=8YFLogxK
U2 - 10.1002/ejoc.202200701
DO - 10.1002/ejoc.202200701
M3 - Review article
AN - SCOPUS:85138431393
VL - 2022
JO - European Journal of Organic Chemistry
JF - European Journal of Organic Chemistry
SN - 1434-193X
IS - 41
M1 - e202200701
ER -