Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Reda M. Mohamed
  • Detlef Bahnemann
  • Amal S. Basaleh
  • Ratzen H. Qadah

Research Organisations

External Research Organisations

  • King Abdulaziz University
  • Saint Petersburg State University
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Details

Original languageEnglish
Pages (from-to)931-939
Number of pages9
JournalApplied Nanoscience (Switzerland)
Volume10
Issue number3
Publication statusPublished - 4 Sept 2019

Abstract

The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.

Keywords

    Acetaldehyde, Cobalt, Copper, Titania, Visible light

ASJC Scopus subject areas

Cite this

Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light. / Mohamed, Reda M.; Bahnemann, Detlef; Basaleh, Amal S. et al.
In: Applied Nanoscience (Switzerland), Vol. 10, No. 3, 04.09.2019, p. 931-939.

Research output: Contribution to journalArticleResearchpeer review

Mohamed RM, Bahnemann D, Basaleh AS, Qadah RH. Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light. Applied Nanoscience (Switzerland). 2019 Sept 4;10(3):931-939. doi: 10.1007/s13204-019-01157-4
Mohamed, Reda M. ; Bahnemann, Detlef ; Basaleh, Amal S. et al. / Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light. In: Applied Nanoscience (Switzerland). 2019 ; Vol. 10, No. 3. pp. 931-939.
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title = "Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light",
abstract = "The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products. ",
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note = "Funding information: This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support. This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support.",
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AU - Mohamed, Reda M.

AU - Bahnemann, Detlef

AU - Basaleh, Amal S.

AU - Qadah, Ratzen H.

N1 - Funding information: This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support. This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support.

PY - 2019/9/4

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N2 - The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.

AB - The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.

KW - Acetaldehyde

KW - Cobalt

KW - Copper

KW - Titania

KW - Visible light

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JO - Applied Nanoscience (Switzerland)

JF - Applied Nanoscience (Switzerland)

SN - 2190-5509

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