Details
Original language | English |
---|---|
Pages (from-to) | 931-939 |
Number of pages | 9 |
Journal | Applied Nanoscience (Switzerland) |
Volume | 10 |
Issue number | 3 |
Publication status | Published - 4 Sept 2019 |
Abstract
The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.
Keywords
- Acetaldehyde, Cobalt, Copper, Titania, Visible light
ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
- Biotechnology
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Materials Science(all)
- Materials Science (miscellaneous)
- Chemistry(all)
- Physical and Theoretical Chemistry
- Biochemistry, Genetics and Molecular Biology(all)
- Cell Biology
- Engineering(all)
- Electrical and Electronic Engineering
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In: Applied Nanoscience (Switzerland), Vol. 10, No. 3, 04.09.2019, p. 931-939.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Photo-catalytic destruction of acetaldehyde using cobalt, copper co-doped titania dioxide nanoparticles beneath Visible light
AU - Mohamed, Reda M.
AU - Bahnemann, Detlef
AU - Basaleh, Amal S.
AU - Qadah, Ratzen H.
N1 - Funding information: This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support. This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, Saudi Arabia under Grant no. KEP-MSc-3-130-40. The authors, therefore, acknowledge with thanks DSR for technical and financial support.
PY - 2019/9/4
Y1 - 2019/9/4
N2 - The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.
AB - The destruction of acetaldehyde (CH 3CHO) photo-catalytically beneath Vis light irradiation using Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co co-doped TiO 2 (8 × 10 −2 mol%) nanoparticles have been investigated. The results reveal that Cu doped TiO 2 (8 × 10 −2 mol%), Co-doped TiO 2 (8 × 10 −2 mol%) and Cu, Co codoped TiO 2 (8 × 10 −2 mol%) nanoparticles are efficient photo-catalysts for the destruction of CH 3CHO using Vis light illumination. Co, Cu-codoped TiO 2 specimen displayed the biggest speed value of carbon dioxide gas evolution, achieving 990 ppm of carbon dioxide gas at the end of 300 min of Vis light illumination, that was 1.1, 1.3 and 99 much greater than that of Co-doped TiO 2, Cu-doped TiO, and titania, respectively. Due to doping of metal enhance photocatalytic activity by enhancing generated electron–hole pairs or retard the re-consolidation speed of electrons and holes. The major products from photo-catalytic destruction of acetaldehyde are H 2O and CO 2. Therefore, 0.08 mol% Co, Cu co-doped TiO 2 photo-catalyst is regarded as safe photo-catalyst for complete degrade of acetaldehyde under visible light from indoor atmospheric environments without produce toxic by-products.
KW - Acetaldehyde
KW - Cobalt
KW - Copper
KW - Titania
KW - Visible light
UR - http://www.scopus.com/inward/record.url?scp=85071765512&partnerID=8YFLogxK
U2 - 10.1007/s13204-019-01157-4
DO - 10.1007/s13204-019-01157-4
M3 - Article
VL - 10
SP - 931
EP - 939
JO - Applied Nanoscience (Switzerland)
JF - Applied Nanoscience (Switzerland)
SN - 2190-5509
IS - 3
ER -